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Fig. 2. Molecular structure of 3′-Ag in the solid state as determined by X-ray crystallography. Thermal ellipsoids set at the 50% probability level. Hydrogen atoms omitted and iPr groups shown in wireframe for clarity. Key bond lengths (Å) and angles (°): Ga(1)–O(1) 2.3834(14), Ga(1)–Ag(1) 2.4548(3), Ag(1)–P(1) 2.4355(6), Ga(1)–Ag(1)–P(1) 175.00(2).