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Fig. 4. Molecular structure of 5-Ag in the solid state as determined by X-ray crystallography. Thermal ellipsoids set at the 50% probability level. Hydrogen atoms omitted and iPr/tBu shown in wireframe for clarity. Key bond lengths (Å) and angles (°): Ag(1)–C(48): 2.118(2), Ag(1)–P(1): 2.3851(6), N(3)–C(48): 1.346(3), N(4)–C(48): 1.345(3).