Table 2. Pseudo-First-Order Kinetic Constants along with Regression Values at Different Cr(VI) and H2O2 Concentrationsa.
parameters | k1 (min–1) | R2 | |
---|---|---|---|
Cr(VI) | 1 mM | 0.039 ± 0.001 | 0.9893 |
2 mM | 0.049 ± 0.002 | 0.9808 | |
3 mM | 0.076 ± 0.003 | 0.9974 | |
5 mM | 0.062 ± 0.003 | 0.9066 | |
7 mM | 0.032 ± 0.001 | 0.9652 | |
H2O2 | 7.8 mM | 0.032 ± 0.001 | 0.9848 |
11.64 mM | 0.039 ± 0.001 | 0.9771 | |
15.52 mM | 0.051 ± 0.002 | 0.9779 | |
19.4 mM | 0.098 ± 0.004 | 0.9011 | |
23.28 mM | 0.042 ± 0.001 | 0.9636 | |
27.16 mM | 0.032 ± 0.001 | 0.9390 |
When the Cr(VI) and H2O2 concentrations were varied, respectively, other parameters were held constant: pH = 6, temperature = 298 K, [MB] = 15.7 μM, [Cr(VI)] = 3 mM, and [H2O2] = 19.4 mM.