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. 2021 Oct 11;9(10):259. doi: 10.3390/toxics9100259

Table 3.

Results of studies conducted in people with As exposure and supplementation with folic acid or zinc.

Reference Research Model Study Description Main Results
Gamble et al., 2007 [45] Bangladesh, adults CG (n = 62)—placebo (orally, for 12 weeks)
G1 (N = 68)—folic acid 400 µg/day (orally, for 12 weeks)
G1 vs. CG
blood: MMA↓, tAs↓, DMA↔
urine: DMA↑ (after 1 week) DMA↔(after 12 week)
Bozack et al., 2019 [46] Bangladesh, adults CG (n = 90)—placebo (orally, for 12 weeks)
G1 (n = 133)—folic acid 400 µg/day (orally, for 12 weeks)
G2 (n = 129)—folic acid 800 µg/day (orally, for 12 weeks)
G1, G2 vs. CG
plasma: folate↑, homocysteine↓
RBC folate↑
urine: %iAs↓, %MMAs↓, %DMAs↑
G2 vs. G1
urine: %MMAs↓
G1 (n = 68)—folic acid 400 µg/day (orally, for 12 weeks) and after that placebo (orally, for 12 weeks)
G2 (n = 60)—folic acid 800 µg/day (orally, for 12 weeks) and after that placebo (orally, for 12 weeks)
G1a (n = 65)—folic acid 400 µg/day (orally, for 24 weeks)
G2a (n = 69)—folic acid 800 µg/day (orally, for 24 weeks)
G1a, G2a vs. G1, G2
urine: %iAs↓, %MMAs↓, %DMAs↑
Peters et al., 2015 [47] Bangladesh, adults CG (n = 102)—placebo (orally, for 12 weeks)
G1 (n = 153)—folic acid 400 µg/day (orally, for 12 weeks)
G2 (n = 151)—folic acid 800 µg/day (orally, for 12 weeks)
G1 vs. CG
plasma folate↑, RBC folate↑, geometric mean of blood tAs↑, percentage decline in geometric mean blood tAs from baseline↓
G2 vs. CG
plasma folate↑, RBC folate↑, geometric mean of blood tAs↓, percentage decline in geometric mean blood tAs from baseline↑
CG (n = 102)—placebo (orally, for 24 weeks)
G1 (n = 76)—folic acid 400 µg/day (orally, for 12 weeks) and after that placebo (orally, for 12 weeks)
G2 (n = 74)—folic acid 800 µg/day (orally, for 12 weeks) and after that placebo (orally, for 12 weeks)
G1a (n = 77)—folic acid 400 µg/day (orally, for 24 weeks)
G2a (n = 77)—folic acid 800 µg/day (orally, for 24 weeks)
G2, G2a vs. CG
geometric mean of blood tAs↓
G1a vs. G1
geometric mean of blood tAs↔, percentage decline in geometric mean of urinary and blood tAs↔
G2a vs. G2
geometric mean of blood tAs↔, percentage decline in geometric mean of urinary and blood tAs↔
Bozack et al., 2020 [48] Bangladesh, adults CG (n = 104)—placebo (orally, for 12 weeks)
G1 (n = 156)—folic acid 400 µg/day (orally, for 12 weeks)
G2 (n = 154)—folic acid 800 µg/day (orally, for 12 weeks)
G1 vs. CG
participants with betaine concentrations below the median: urine: decreases in ln(%iAs)↑, decrease in %MMAs↑, increases in %DMAs↑
G2 vs. CG
participants with betaine concentrations below the median: urine: decreases in ln(%iAs)↑, increases in %DMAs↑
Kordas et al., 2017 [49] Mexico, children (6–7 years) CG (n = 151)—placebo (orally, for 6 months)
G1 (n = 144)—zinc oxide 30 mg/day (orally, for 6 months)
G1 vs. CG
urine: %DMA↓, %MMA↔, %iAs↔, tAs↔
Hall et al., 2016 [50] Bagladesh, adults CG (n = 101)—placebo (participants received arsenic-removal water filters and had been drinking water from wells with water As concentration >50 µg/L at least 3 years)
G1 (n = 152)—folic acid 400 µg/day (orally, for 12 weeks) and after that placebo (participants received arsenic-removal water filters and had been drinking water from wells with water As concentration >50 µg/L at least 3 years)
G2 (n = 149)—folic acid 800 µg/day (orally, for 12 weeks) and after that placebo (participants received arsenic-removal water filters and had been drinking water from wells with water As concentration >50 µg/L at least 3 years)
G1, G2 vs. CG
plasma: choline↑, betaine↑, percentage decrease in DMG↑
G1 vs. G2
plasma: choline↔, betaine↔, percentage decrease in DMG↔
Dani, 2019 [51] Women (16 year-old)—chronic arsenic intoxication ex juvantibus therapy: torasemide 10–20 mg/day, thiamine 300 mg/day, magnesium 5 mg/day, folic acid 5 mg/day and metamizole and simeticon (on-demand) nuchal scalp hair shafts: As—undetectable
morning urine: As—undetectable
afternoon urine: As 50 nmol/L
symptoms (leg cramps, abdominal pains)↓
Howe et al., 2017 [52] Bangladesh, adults CG (n = 104)—placebo (orally, for 12 weeks)
G1 (n = 156)—folic acid 400 µg/day (orally, for 12 weeks)
G1 vs. CG
blood: PTHMs↔
Ghose et al., 2014 [53] India, patients with symptoms of arsenic toxicity CG (n = 45)—drinking arsenic free water (orally, for 6 months)
G1 (n = 32)—folic acid 5 mg/day (orally, for 6 months)
G1 vs. CG
skin score↓, systemic disease score↑ (overall: clinical symptoms of arsenicosis↓)

↑—significant increase; ↓—significant decrease; ↔—no significant changes; CG—control group; DMA—dimethylarsinic acid; DMAs—dimethyl arsenical species; DMG—dimethylglycine; G1—group 1; G2—group 2; iAs—inorganic arsenic; MMA—monomethylarsonic acid; MMAs—monomethyl arsenical species; PTHMs—post-translational histone modifications; RBC—red blood cell; tAs—total arsenic species.