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. Author manuscript; available in PMC: 2022 Apr 28.
Published in final edited form as: J Am Chem Soc. 2021 Apr 15;143(16):6065–6070. doi: 10.1021/jacs.1c02747

Table 2.

Scope of Photocatalytic Oxidative Heterofunctionalization[a]

graphic file with name nihms-1748416-t0005.jpg
[a]

Reaction conditions: substrate (0.3 mmol, 1 equiv), MesAcrPh+ (2.5 mol%), Cu(EH)2 (2 equiv), TFA (1 equiv), and 1,2-DCE. irradiated for 8–96 h. Diastereomer and regioisomer ratios were determined by 1H NMR analysis of the unpurified reaction mixtures.

[b]

p-TsOH (2 equiv) instead of TFA.

[c]

p-TsOH (1 equiv) instead of TFA.

[d]

Reaction irradiated for 30 min.