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Chemical structures of Avi(Me)Cys-containing peptides of the thioamitide family; thioholgamide A (19),44 thioviridamide (20),5 thiostreptamide S4 (21),45 thioholgamide B (22),44 thiosparsoamide (23),46 JBIR-140 (24),48 TVA-YJ-4 and 5 (epimers at α-hydroxyamide) (25),43 thioalbamide (26),47 TVA-YJ-6 (27),43 and TVA-YJ-1 (28).43 Pink = Avi(Me)Cys.
