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Jadomycin chemical structure and key analogs. (A) Jadomycin backbone structure with A‐, B‐, C‐, D‐, and E‐rings, and deoxy sugar attached to D‐ring. “R1”‐group indicates location of =O or ‐H attachment, creating an oxazolone or oxazolidine ring, respectively, while “R2”‐group indicates attachment of amino acid analog (B) jadomycin B, L‐Isoleucine, (C) jadomycin S, L‐Serine, or (D) jadomycin F, L‐Phenylalanine
