. 2021 Oct 18;69(42):12527–12540. doi: 10.1021/acs.jafc.1c01382

Table 1. Concentrations of Macro-and Micronutrients in the Roots and Shoots of L.sativa Root Exposed to NPATZ and ATZ with Concentrations Ranging from Low, Medium, To High and Different Exposure Durations (Short-, Medium-, And Long-Term)^a.

		root (mg/kg)							shoot (mg/kg)
		K	Mg	B	Fe	Zn	Mn	Cu	K	Mg	B	Fe	Zn	Mn	Cu
short-term	CK	31500 ± 248a	6470 ± 910ab	72.0 ± 21.0a	5210 ± 862a	123 ± 14ab	102 ± 33ab	64 ± 7ab	45700 ± 5030a	2630 ± 189a	41 ± 3abc	751 ± 109ab	49 ± 5a	55 ± 5a	–
	NPC	45200 ± 4580b	5620 ± 500a	109 ± 9ab	5210 ± 964a	140 ± 19ab	99 ± 12a	70 ± 9a	60000 ± 14100a	2650 ± 539a	38 ± 7ab	684 ± 130a	54 ± 8a	68 ± 16a	–
	NPATZ_L	47500 ± 1950bc	5770 ± 590a	116 ± 24abc	6140 ± 705ab	120 ± 18a	107 ± 8ab	53 ± 7abc	62600 ± 5370a	3280 ± 281ab	61 ± 6bcd	1280 ± 382abc	75 ± 11ab	83 ± 15a	–
	NPATZ_M	50300 ± 142bc	9320 ± 220c	135 ± 31abc	7650 ± 608bc	125 ± 6ab	106 ± 7ab	43 ± 1c	68400 ± 571a	4230 ± 409b	65 ± 11 cd	1450 ± 386abc	108 ± 17ab	99 ± 18a	–
	NPATZ_H	58100 ± 503c	7380 ± 280ab	187 ± 12c	7830 ± 333bc	168 ± 22ab	124 ± 7ab	58 ± 5abc	72600 ± 4750a	3910 ± 215ab	67 ± 6d	1220 ± 158abc	151 ± 59b	80 ± 6a	–
	ATZ_L	41100 ± 2450ab	7880 ± 750bc	176 ± 23bc	8630 ± 1140c	159 ± 33ab	146 ± 14 ab	40 ± 3c	69400 ± 9760a	3440 ± 377ab	52 ± 4abcd	1080 ± 280abc	136 ± 36ab	82 ± 13a	–
	ATZ_M	45200 ± 5640b	6760 ± 120ab	140 ± 14abc	9840 ± 580c	182 ± 6ab	176 ± 33b	48 ± 3bc	59600 ± 3040a	3440 ± 354ab	36 ± 5a	1820 ± 300c	134 ± 16ab	83 ± 11a	–
	ATZ_H	37800 ± 3810ab	6470 ± 670ab	192 ± 35c	8840 ± 465c	233 ± 79b	147 ± 38ab	51 ± 9abc	55400 ± 14700a	3070 ± 620ab	46 ± 12abcd	1570 ± 165bc	125 ± 9ab	84 ± 34a	–

medium-term	CK	51800 ± 2490abc	11700 ± 650a	237 ± 16a	9170 ± 710a	157 ± 17ab	170 ± 20a	219 ± 11a	34300 ± 1380a	4550 ± 362a	81 ± 11ab	682 ± 40ab	74 ± 16ab	96 ± 14a	–
	NPC	48900 ± 3600ab	9290 ± 400a	258 ± 79a	9520 ± 1640a	143 ± 9a	133 ± 24a	252 ± 18a	85400 ± 11000ab	5130 ± 901a	75 ± 14ab	685 ± 157ab	56 ± 4a	116 ± 24ab	–
	NPATZ_L	54500 ± 2790abc	10500 ± 320a	180 ± 64a	6050 ± 670a	176 ± 14ab	135 ± 31a	170 ± 28ab	100000 ± 7080ab	5900 ± 590a	101 ± 9ab	603 ± 108a	60 ± 13a	111 ± 6ab	–
	NPATZ_M	64600 ± 5750 cd	9380 ± 790a	191 ± 10a	9420 ± 770a	266 ± 46bc	158 ± 37a	169 ± 1ab	130000 ± 19600b	8380 ± 1230a	132 ± 16ab	1940 ± 181b	123 ± 16b	227 ± 22c	–
	NPATZ_H	60500 ± 3540bcd	10100 ± 870a	118 ± 5a	6650 ± 2310a	193 ± 29ab	122 ± 39a	228 ± 35a	126000 ± 33700b	5960 ± 1620a	107 ± 32ab	1390 ± 280ab	69 ± 15ab	196 ± 52bc	–
	ATZ_L	44400 ± 2500a	9260 ± 640a	200 ± 38a	9950 ± 1110a	169 ± 25ab	210 ± 62a	136 ± 22b	70100 ± 5500ab	4380 ± 307a	61 ± 9a	1050 ± 316ab	107 ± 30ab	120 ± 19ab	–
	ATZ_M	62700 ± 4620 cd	11200 ± 1000a	461 ± 65b	10800 ± 1380a	324 ± 63c	176 ± 52a	127 ± 32b	118000 ± 34600b	7230 ± 2010a	128 ± 52ab	1830 ± 936ab	109 ± 29ab	143 ± 37abc	–
	ATZ_H	69600 ± 5470d	10900 ± 550a	222 ± 51a	10500 ± 1830a	262 ± 20bc	151 ± 13a	121 ± 33b	125000 ± 44700b	7430 ± 2660a	171 ± 47b	747 ± 76ab	92 ± 12ab	89 ± 16a	–

long-term	CK	87000 ± 7780a	16600 ± 2540a	182 ± 40ab	10100 ± 694ab	240 ± 23a	203 ± 30a	299 ± 41a	86800 ± 2320a	5250 ± 287ab	96 ± 6a	1130 ± 120a	77 ± 2a	143 ± 27a	–
	NPC	75900 ± 7410a	14100 ± 132ab	150 ± 21ab	10100 ± 1360ab	204 ± 22a	175 ± 28a	332 ± 21a	80700 ± 4950a	5610 ± 206b	100 ± 21a	1300 ± 254a	70 ± 16a	133 ± 7a	–
	NPATZ_L	40500 ± 3490b	10000 ± 1260bc	114 ± 11bc	10600 ± 2670a	267 ± 38a	157 ± 18a	303 ± 3a	35400 ± 5560c	5200 ± 356ab	56 ± 1bc	1090 ± 47a	53 ± 15a	136 ± 47a	–
	NPATZ_M	39100 ± 129b	8330 ± 1360bc	180 ± 13ab	5090 ± 57c	231 ± 6a	137 ± 2a	246 ± 3ab	50100 ± 4330bc	4800 ± 317ab	54 ± 17bc	550 ± 28b	--	125 ± 22a	–
	NPATZ_H	40800 ± 3420b	7510 ± 12c	35 ± 10c	4060 ± 231c	153 ± 22a	123 ± 10a	169 ± 28b	38400 ± 12200c	4450 ± 165a	41 ± 7c	694 ± 53bc	--	120 ± 19a	–
	ATZ_L	44900 ± 3310b	11100 ± 1500abc	156 ± 17ab	6420 ± 932bc	216 ± 36a	134 ± 19a	317 ± 16a	54600 ± 5780bc	4550 ± 478a	87 ± 4ab	1060 ± 62ac	37 ± 17a	99 ± 18a	–
	ATZ_M	62400 ± 14200ab	9070 ± 1140bc	214 ± 15a	5170 ± 632c	415 ± 35b	141 ± 0.1a	185 ± 10b	65300 ± 8090ab	4730 ± 282ab	62 ± 13abc	1010 ± 80ac	45 ± 22a	94 ± 9a	–
	ATZ_H	34478 ± 16200b	5830 ± 2660c	105 ± 15bc	4620 ± 394c	222 ± 69a	129 ± 29a	175 ± 24b	33900 ± 4750c	5080 ± 227ab	25 ± 9c	1120 ± 143a	–	112 ± 31a	–

Data are mean ± SE (n = 3). The different letters indicate significant differences between treatments within the same exposure duration by one-way ANOVA and Duncan’s honestly significant difference tests at α < 0.05. CK: control check, control plants without exposure to chemicals. NPC: exposure to a polymeric carrier without the ATZ (control). NPATZ-L: exposure to a low concentration of NPATZ. NPATZ-M: exposure to a medium concentration of NPATZ. NPATZ-H: exposure to a high concentration of NPATZ. ATZ-L: exposure to a low concentration of ATZ. ATZ-M: exposure to a medium concentration of ATZ. ATZ-H: exposure to a high concentration of ATZ. – means the concentration of the tested element were below the detection limits. The Cu content in plants shoots in all treatments were undetectable regardless of the exposure duration.

Table 1. Concentrations of Macro-and Micronutrients in the Roots and Shoots of L.sativa Root Exposed to NPATZ and ATZ with Concentrations Ranging from Low, Medium, To High and Different Exposure Durations (Short-, Medium-, And Long-Term)a.

Table 1. Concentrations of Macro-and Micronutrients in the Roots and Shoots of L.sativa Root Exposed to NPATZ and ATZ with Concentrations Ranging from Low, Medium, To High and Different Exposure Durations (Short-, Medium-, And Long-Term)^a.