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. 2021 Oct 15;60(21):16397–16408. doi: 10.1021/acs.inorgchem.1c02211

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© 2021 The Authors. Published by American Chemical Society

Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).

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Upper part: Comparison between the two structures of Ho₂Ni_0.8Si_1.2 (Zr₂Ni_0.48P type; oP32; Pnma) and Ho₃NiSi₂ (Gd₃NiSi₂ type; oP24; Pnma), showing characteristic trigonal-prismatic coordination and similar orientation and concatenation of the respective structural motifs. Lower part: Linking of the trigonal prisms in the binary compounds HoNi (FeB type) and HoSi (low-temperature CrB type).