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. 2021 Oct 21;60(21):16713–16725. doi: 10.1021/acs.inorgchem.1c02582

Table 2. M–M and M–CO (M = Ni or Pd) Connectivities of Ni–Pd Carbonyl Clusters Reported as Intervals.

  Ni
Pd
Ni–M Ni–CO Pd–M Pd–CO
[Ni13Pd13(CO)34]4–a 3–7 3 6–12 2
[Ni16Pd16(CO)40]4–b 5–6 3–4 7–12 0–2
[Ni29–xPd6+x(CO)42]6–c 4–8 2–3 8–12 0–2
[Ni29+xPd6–x(CO)42]6–c 4–8 2–3 8–12 0–3
16– 3–8 2–4 8–12 0–3
[Ni22–xPd20+x(CO)48]6–c 3–9 3–4 8–12 0–3
35– 4–9 2–3 9–12 0–3
26– 4–9 2–3 9–12 0–3
[Ni36Pd8(CO)48]6–d 4–9 2–3 9–12 0–2
a

See ref (46).

b

See ref (47).

c

See ref (14).

d

See ref (45).