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. 2021 Oct 21;60(21):16713–16725. doi: 10.1021/acs.inorgchem.1c02582

Table 5. Infrared Stretching Frequencies (cm–1) of the Terminal (νtCO) and Bridging (νbCO) Carbonyl Groups for 3n in CH3CN as a Function of Cluster Charge n.

cluster charge n νtCO νbCO
–4 2013 1870
–5 2002 1860
–6 1987 1846
–7 1972 1832
–8 1957 1818