Table 2. Kinetic Data for the Dehydrogenation of Formic Acid Catalyzed by 2.
| T (K) | [cat.] (102 M) | [HCOOH] (M) | d[H2]/dt (102 M min–1) | k (min–1) |
|---|---|---|---|---|
| 373 | 0.26 | 0.26 | 0.241 | 0.912 |
| 373 | 0.53 | 0.26 | 0.589 | 1.110 |
| 373 | 0.79 | 0.26 | 0.830 | 1.045 |
| 373 | 1.06 | 0.26 | 0.895 | 0.845 |
| 373 | 1.32 | 0.26 | 1.277 | 0.965 |
| 373 | 0.53 | 0.40 | 0.589 | 1.112 |
| 373 | 0.53 | 0.53 | 0.465 | 0.877 |
| 373 | 0.53 | 0.66 | 0.459 | 0.866 |
| 373 | 0.53 | 0.79 | 0.477 | 0.899 |
| 363 | 0.53 | 0.26 | 0.306 | 0.577 |
| 353 | 0.53 | 0.26 | 0.159 | 0.300 |
| 343 | 0.53 | 0.26 | 0.100 | 0.189 |
| 333 | 0.53 | 0.26 | 0.088 | 0.167 |