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. 2021 Oct 12;12(42):14004–14023. doi: 10.1039/d1sc03908c

OPV performance with χ and ISI value for polymer donor:FA and polymer donor:NFA.

Acceptor Donor V OC [V] J SC [mA cm−2] FF [%] PCE [%] χ aa ISI Ref.
FAs
PC71BM PDPP3T 0.66 15.4 66 6.6 1.39 (Tm)a 1 174 and 183
PC71BM PTFB-P 0.81 12.9 72 7.5 1.70 (Tm)a 174 and 184
PC71BM PffBT4T-2DT 0.76 16.2 62 7.6 1.56 (Tm)a 174 and 185
PC71BM PffBTT2-DPPT2 0.81 17.1 61 8.6 1.53 (Tm)a 174 and 186
PC71BM PffBT4T-2OD 0.77 18.4 74 10.5 1.36 (Tm)a 1 22 and 174
PC71BM PffBT-T3 0.82 18.9 69 10.7 1.60 (Tm)a 174 and 187
PC71BM PffBT4T-C9C13 0.78 19.8 73 11.7 1.70 (Tm)a 1 23 and 174
PDI-based NFAs
SF-PDI2 PffBT4T-2OD 0.97 6.9 43 2.9 0.25 (Tm)a 174
diPDI PffBT-T3 0.86 12.8 46 5.1 0.83 (Tm)a 0.56 174
TPE-PDI4 PffBT-T3 1.02 11.5 48 5.7 0.23 (Tm)a 0.32 174
SF-PDI2 PffBT-T3 1.03 12.3 49 6.2 0.70 (Tm)a 0.52 174
IDT-based NFAs
IEIC PffBT-T3 1.04 12.6 59 7.7 1.08 (Tm)a 0.83 174
ITIC-Th PTFB-P 0.92 15.5 65 9.2 1.01 (Tm)a 0.91 174
ITIC-Th PTFB-O 0.92 17.1 68 10.9 1.70 (Tm)a 1 174
IT-DM PBDB-T 0.96 16.3 69 11.3 2.0 (HSP)b 0.83 188
IT-M PBDB-T 0.94 17.3 71 12.1 2.7 (HSP)b 0.97 188
IT-4F P1 0.90 20.1 64 11.5 0.15 Kc 189
IT-4F P2 0.90 20.7 76 14.2 0.25 Kc 189
IT-4F P3 0.90 20.3 61 11.2 0.19 Kc 189
Y6-based NFAs
Y6 PM6 0.86 25.5 72 15.8 0.20 Kc 190
Y6 PM1 0.87 25.9 78 17.6 0.26 Kc 190
BTP-4Cl P3HT 0.50 5.16 39 1.01 2.52 (HSP)b 191
ZY-4Cl P3HT 0.88 16.5 65 9.46 2.56 (HSP)b 191
a

The value obtained from DSC.

b

HSP.

c

Contact angle measurement.