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. 2021 Nov 4;11:21672. doi: 10.1038/s41598-021-00701-z

Table 9.

Electrochemical parameters obtained from EFM technique for the corrosion of carbon steel in 1 M HCl at various concentrations of carbonitrile compounds at 25 °C.

Comp. Conc, M icorr. μA cm−2 βa, mV dec−1 − βc, mV dec−1 CF(2) CF(3) %η
1.0 M HCl, Blank 299.2 ± 0.2009 93.7 ± 0.1453 101.3 ± 0.2027 1.89 2.96
PdC-OH 2 × 10–5 62.8 ± 0.2235 82.5 ± 0.1732 102.1 ± 0.2906 1.17 2.70 79.0
4 × 10–5 56.4 ± 0.2127 83.6 ± 0.2309 111.6 ± 0.1732 1.65 2.63 81.2
6 × 10–5 52.7 ± 0.2033 72.1 ± 0.1732 89. 7 ± 0.1763 1.97 3.22 82.4
8 × 10–5 71. 5 ± 0.1764 74.0 ± 0.2309 87.0 ± 0.2082 1.40 2.71 88.6
1 × 10–4 67.6 ± 0.1551 85.0 ± 0.2102 107.0 ± 0.2028 1.82 2.69 89.2
PdC-Me 2 × 10–5 91.8 ± 0.1614 93.8 ± 0.1732 104.3 ± 0.2028 1.97 3.20 69.3
4 × 10–5 89.8 ± 0.1301 92.9 ± 0.2101 103.1 ± 0.2123 1.57 3.47 70.3
6 × 10–5 68.5 ± 0.1564 79.0 ± 0.2423 93.1 ± 0.2234 2.22 2.91 77.1
8 × 10–5 65.1 ± 0.2603 76.1 ± 0.2512 111.2 ± 0.2131 2.04 2.59 78.3
1 × 10–4 64.20.2028 69.3 ± 0.1202 76.2 ± 0.2028 2.08 2.47 78.5
PdC-H 2 × 10–5 92.3 ± 0.2028 108.3 ± 0.2333 133.2 ± 0.1732 2.20 2.66 69.2
4 × 10–5 88.9 ± 0.2906 95.4 ± 0.1453 110.7 ± 0.2309 1.90 2.70 70.3
6 × 10–5 80.0 ± 0.1732 106.1 ± 0.2027 123.1 ± 0.1453 1.95 3.48 73.3
8 × 10–5 70.6 ± 0.2028 96.7 ± 0.20223 129.8 ± 0.2028 1.88 2.99 76.4
1 × 10–4 70.3 ± 0.2082 86.3 ± 0.1027 99.9 ± 0.1453 2.25 3.22 76.5