Table 1. Summary of the Cation Transference Numbers and Salt Diffusion Coefficients Derived from the Galvanostatic Polarization Method (Supporting Information, Figure S9)a.
electrolytes | tpol | Dsalt (cm2 s–1) |
---|---|---|
1M LiTf in triglyme | 0.24 | 1.0 × 10–7 |
1M LiTf in EC/DMC | 0.12 | 2.8 × 10–6 |
1M NaTf in triglyme | 0.42 (tEIS = 0.36) | 1.7 × 10–6 |
1M NaTf in EC/DMC | N/A | 5.8 × 10–8 |
tEIS: the transference number measured by the low-frequency EIS method (Supporting Information, Figure S10).