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. 2021 Oct 7;28(Pt 6):1825–1838. doi: 10.1107/S1600577521008389

Table 2. Parameters used to obtain experimental S 3p character for TU complexes of Co2+ and Ni2+ .

  D 0 (unit) E_0^{\,\rm{L}} (eV) I L (unit) E_0^{\,\rm{L}} (eV) Slope I C (unit) S 3p (e per hole)
[Ni(TU)6]2+ 0.53 ± 0.3 2474.6 ± 0.5 C-based 7.6 ± 0.8 0.5 29.2 22.2 0.21 ± 0.05
N-based 17.6 ± 0.8 32.2 0.15 ± 0.05
[Co(TU)4]2+ 0.56 ± 0.4 C-based 7.6 ± 0.8 0.6 25.1 0.09 ± 0.04
N-based 17.6 ± 0.8 35.1 0.06 ± 0.04