Table 2. Parameters used to obtain experimental S 3p character for TU complexes of Co2+ and Ni2+ .
| D 0 (unit) | E_0^{\,\rm{L}} (eV) | I L (unit) | E_0^{\,\rm{L}} (eV) | Slope | I C (unit) | S 3p (e− per hole) | ||
|---|---|---|---|---|---|---|---|---|
| [Ni(TU)6]2+ | 0.53 ± 0.3 | 2474.6 ± 0.5 | C-based | 7.6 ± 0.8 | 0.5 | 29.2 | 22.2 | 0.21 ± 0.05 |
| N-based | 17.6 ± 0.8 | 32.2 | 0.15 ± 0.05 | |||||
| [Co(TU)4]2+ | 0.56 ± 0.4 | C-based | 7.6 ± 0.8 | 0.6 | 25.1 | 0.09 ± 0.04 | ||
| N-based | 17.6 ± 0.8 | 35.1 | 0.06 ± 0.04 | |||||