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A) Scan rate studies of the first reduction potential for pyridinium salt 1c-Cy. B) Experimental (solid) vs Simulated (dashed) of 1c-Cy first reduction at different scan rates. Simulation parameters: E0 = −1.34V vs Fc+/Fc, ks = 0.05 cm s−1, kf = 0.01 s-1. C) Experimentally determined rate constants of radical dissociation of 2 vs DFT-computed values.
