Table 2.
Scope of radical amino-cyanation of imidates.
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Conditions: 0.2 mmol imidate, Me3Si-CN (1.8 eq), 1% Ir1, 3% Cu(OTf)2, 7.5% L1, 20:1 MeCN:DMAc (0.05 M), blue LED (455 nm), 18 hrs, 23 °C. Isolated yields; dr by NMR.
Scope of radical amino-cyanation of imidates.
|
Conditions: 0.2 mmol imidate, Me3Si-CN (1.8 eq), 1% Ir1, 3% Cu(OTf)2, 7.5% L1, 20:1 MeCN:DMAc (0.05 M), blue LED (455 nm), 18 hrs, 23 °C. Isolated yields; dr by NMR.