Table 2. Scope of Different ArMgBr Reagents in the Reaction with Triflate 5aa,b,c.
Reaction conditions: 5a (0.13 mmol), ArMgBr (0.195 mmol), THF (2 mL).
Isolated yields of product.
Numbers in parentheses indicate yields according to 31P NMR.
Reaction was carried out on a 0.6 mmol scale.
Reaction was carried out with o-TolMgCl.
Formation of a small amount of ketone 3a was observed but not isolated.
Additionally, 7% of 3a was isolated.

