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. 2021 Oct 26;86(21):14928–14941. doi: 10.1021/acs.joc.1c01629

Table 3. Reactivity of Substituted Benzophosphole Oxides 5bd with Aryl Grignard Reagentsa,b,c.

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a

Reaction conditions: 5a (0.13 mmol), ArMgBr (0.195 mmol), THF (2 mL).

b

Isolated yields of product.

c

Numbers in parentheses indicate yields according to 31P NMR.

d

Formation of a small amount of ketone 3a was observed but not isolated.