Table 2. Summary of the Photocatalytic Performance by Ru(II)–Ni(II)- and Ru(II)–Co(III)-Based Systemsa.
entry | photocatalyst | reductant | product formed | selectivity (%) | TON | reference |
---|---|---|---|---|---|---|
1 | S1 | ascorbic acid | CO | 72 | <1 | (102) |
2 | [Ru(Phen)3]2+ + [Ni(cyclam)]2+ | ascorbic acid | CO | 36 | <1 | (102) |
3 | S2 | ascorbic acid | CO | 11 | <1 | (95) |
4 | [Ru(bpy)3]2+ + Ni moiety (as in S2) | ascorbic acid | CO | 09 | 2 | (95) |
5 | S3 | TEOA | CO | 50 | 2 | (105) |
6 | [Ru(bpy)3]2+ + [Ni(bpy)3]2+ | TEOA | CO | 79 | 2 | (105) |
7 | S4 | TEOA | CO | 73 | 3 | (105) |
8 | S5 | TEOA | CO | 79 | 5 | (105) |
9 | [Ru(bpy)3]2+ + [Co(bpy)3]3+ | TEOA | CO | 35 | 9 | (105) |
Reproduced with permission from ref (53). Copyright [2017] [American Chemical Society].