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. 2021 Oct 26;6(44):29291–29324. doi: 10.1021/acsomega.1c04018

Table 2. Summary of the Photocatalytic Performance by Ru(II)–Ni(II)- and Ru(II)–Co(III)-Based Systemsa.

entry photocatalyst reductant product formed selectivity (%) TON reference
1 S1 ascorbic acid CO 72 <1 (102)
2 [Ru(Phen)3]2+ + [Ni(cyclam)]2+ ascorbic acid CO 36 <1 (102)
3 S2 ascorbic acid CO 11 <1 (95)
4 [Ru(bpy)3]2+ + Ni moiety (as in S2) ascorbic acid CO 09 2 (95)
5 S3 TEOA CO 50 2 (105)
6 [Ru(bpy)3]2+ + [Ni(bpy)3]2+ TEOA CO 79 2 (105)
7 S4 TEOA CO 73 3 (105)
8 S5 TEOA CO 79 5 (105)
9 [Ru(bpy)3]2+ + [Co(bpy)3]3+ TEOA CO 35 9 (105)
a

Reproduced with permission from ref (53). Copyright [2017] [American Chemical Society].