Table 3. Summary of the Photocatalytic Performance by Various Ru(II)–Re(I)-Based Supramolecules Involving One or More Photosensitizers and/or Catalyst Components^a.

entry	photocatalyst	reductant	product	selectivity (%)	TON	reference
10	S12	BNAH	CO	96	170	(52)
11	[Ru(4dmb)3]2+ + fac-Re(4dmb)(CO)3Cl	BNAH	CO/HCOOH	changes from CO to HCOOH	101	(52, 79)
12	S13	BNAH	CO		50	(52)
13	S14	BNAH	CO		03	(52)
14	S15	BNAH	CO		14	(52)
15	S16	BNAH	CO		28	(52)
16	S17	BNAH	CO		240	(52)
17	S18	BNAH	CO	97	232	(111)
18	S19	BNAH	CO	96	97	(111)
19	S20	BNAH	CO	97	180	(79, 112)
20	S21	BNAH	CO		120	(112)
21	S22	BNAH	CO		120	(112)
22	S23	BNAH	CO	94	207	(98)
23		BIH	CO	>99	3029	(113)
24	S24	BNAH	CO	91	144	(98)
25	S25	BNAH	CO	73	27	(98)
26	S26	BNAH	CO	98	233	(53)
27		BIH	CO	>99	2915	(53)
28	S27	BNAH	CO	95	253	(114)
29	S28	BNAH	CO			(114)
30		BIH	CO	>99	>1000	(115)
31	S29	BNAH	CO		123	(116)
32	S30	BNAH	CO		204	(116)
33	S31	sodium ascorbate	HCOOH	81	25	(117)
34	S32	BI(CO2H)H	CO	81	130	(118)
35	S33	BNAH	CO		315	(109)
36	S34	BNAH	CO		50	(109)
37	S35	BNAH	CO		110	(110)
38	S36	BNAH	CO		190	(110)
39	S37	BNAH	CO	69	283	(119)
40	S38	BNAH	CO	75	313	(119)

^aReproduced with permission from ref (53). Copyright [2017] [American Chemical Society].