Table 5. Summary of Performances by Porphyrin–Re(I)-Based Supramolecule Photocatalystsa.
entry | photocatalyst | reductant | product | ϕproduct | TON | reference |
---|---|---|---|---|---|---|
50 | S58 | TEA | CO | 0.0064 | (84) | |
51 | S59 | TEA | CO | 2 | (86) | |
52 | Pd(POR) + fac-[Re(bpy)(CO)3(3-picolene)]+ | TEA | CO | 3 | (86) | |
53 | S60 | TEOA | CO | 14 | (87) | |
54 | S61 | TEOA | CO | 32 | (87) | |
55 | S62 | TEOA | CO | 332 | (151) | |
56 | Zn(POR) + fac-[Re(bpy)(CO)3(3-picolene)]+ | TEOA | CO | 103 | (87) | |
57 | S63 | TEA | CO | 13 | (153) | |
58 | S64 | TEA | CO | <1 | (153) | |
59 | S65 | TEA | CO | <1 | (153) | |
60 | S66 | TEA | CO | <1 | (153) | |
61 | S67 | TEA | CO | <1 | (153) | |
62 | S68 | TEA | CO | <1 | (153) | |
63 | S69 | BIH | CO | 18 | (82) |
Reproduced with permission from ref (53). Copyright [2017] [American Chemical Society].