. 2021 Oct 29;6(44):30157–30172. doi: 10.1021/acsomega.1c05418

Table 1. Ethylene Polymerization Using Ni1_Cl with a Range of Different Cocatalysts^a.

entry	co-cat.	Al/Ni	act.	M_w^b	M_w/M_n^b	T_m^c
1	MAO	2500	2.6	0.9	1.6	91.5, 103.8
2	MMAO	2500	1.2	1.0	1.6	96.4, 106.1, 113.5
3	Me₂AlCl	400	1.7	0.8	1.4	75.6, 99.82
4	EASC	400	1.0	0.8	1.4	75.6, 99.6

General conditions: 2.0 μmol of Ni1_Cl, 100 mL of toluene, 10 atm of ethylene, 30 min, 30 °C, and activity in units of 10⁶ g of PE (mol of Ni)⁻¹ h^–1.

M_w in units of kg mol^–1, determined by GPC.

T_m in units of °C, determined by DSC.

Table 1. Ethylene Polymerization Using Ni1Cl with a Range of Different Cocatalystsa.

Table 1. Ethylene Polymerization Using Ni1_Cl with a Range of Different Cocatalysts^a.