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. 2021 Oct 29;12:754140. doi: 10.3389/fmicb.2021.754140
Water dissociation: 8H2O → 8H+ + 8OH (1)
Anodic reaction: 4Fe + 2H → 4Fe2+ + 8e 2)
Cathodic reaction: 8H+ + 8 e → 8Hads (3)
Cathodic depolarization by hydrogenase: 8Hads → (4H2) → 8H+ + 8 e (4)
Sulfate reduction by SRB SO42– + 8e + 9H+ → HS + 4H2O (5)
Precipitation: Fe2+ + H2S → FeS + 2H+ (6)
Precipitation: 3Fe2+ + 6OH → 3Fe(OH)2 (7)
Total reaction: 4Fe + SO42 + 4H2OFeS + 3Fe(OH)2 + 2OH (8)