Table 2.
RT | Compound | % | KI a | KI b | Identification c | ||
---|---|---|---|---|---|---|---|
EG | EP | ||||||
1 | 5.148 | 1-Methyl-1,3-cyclohexadiene | t | 759 | 1183 | 1,2 | |
2 | 5.267 | 3-Methyl-2-buten-1-ol | t | 761 | 1328 | 1,2 | |
3 | 6.246 | n-Octane | t | 773 | 1,2 | ||
4 | 7.299 | (2Z)-Hexenol | t | 787 | 1,2 | ||
5 | 12.004 | Santolina triene | t | 848 | 1043 | 1,2 | |
6 | 13.849 | α-Pinene | 13.1 | 4.8 | 872 | 1028 | 1,2,3 |
7 | 14.036 | Camphene | 0.1 | 0.1 | 874 | 1075 | 1,2,3 |
8 | 16.071 | β-Pinene | 0.3 | 0.5 | 901 | 1120 | 1,2,3 |
9 | 16.945 | dehydro-1,8 Cineole | t | 912 | 1095 | 1,2 | |
10 | 17.952 | Myrcene | 0.3 | 0.4 | 925 | 1173 | 1,2,3 |
11 | 18.695 | δ-2-Carene | 0.1 | 0.2 | 934 | 1146 | 1,2,3 |
12 | 19.400 | β-Phellandrene | t | 944 | 1206 | 1,2,3 | |
13 | 19.500 | p-Cymene | t | 945 | 1279 | 1,2,3 | |
14 | 20.574 | 1,8-Cineole | 74.7 | 75.5 | 959 | 1220 | 1,2,3 |
15 | 21.870 | (Z)-β-Ocimene | t | 976 | 1240 | 1,2,3 | |
16 | 22.438 | (E)-β- Ocimene | 1.9 | 1.0 | 983 | 1260 | 1,2,3 |
17 | 25.243 | γ-Terpinene | 0.3 | 0.9 | 1016 | 1254 | 1,2,3 |
18 | 27.271 | dehydro-Linalool | 0.5 | 0.5 | 1043 | 1,2 | |
19 | 27.644 | 1,3,8-p-Menthatriene | 0.4 | 1048 | 1,2 | ||
20 | 28.128 | allo-Ocimene | 0.1 | 1055 | 1382 | 1,2 | |
21 | 28.799 | neo-Isopulegol | t | 1064 | 1,2 | ||
22 | 29.513 | Borneol | 0.2 | 1074 | 1715 | 1,2,3 | |
23 | 29.776 | endo-Fenchol | 0.2 | 1.0 | 1077 | 1,2 | |
24 | 31.870 | Terpineol | 4.2 | 1.5 | 1099 | 1710 | 1,2,3 |
25 | 32.268 | cis-Verbenol | 0.2 | 0.1 | 1104 | 1663 | 1,2 |
26 | 34.118 | Verbenone | 0.2 | 0.2 | 1131 | 1,2 | |
27 | 39.679 | Thymol | 0.1 | 0.3 | 1205 | 2172 | 1,2,3 |
28 | 40.403 | δ-Elemene | 0.1 | 1216 | 1460 | 1,2,3 | |
29 | 41.032 | γ-Elemene | 0.1 | 1226 | 1651 | 1,2,3 | |
30 | 41.512 | Myltayl-4(12)-ene | 0.1 | 1233 | 1,2 | ||
31 | 42.079 | dihydro-Eugenol | 0.5 | 7.5 | 1242 | 1,2 | |
32 | 43.444 | α-Copaene | t | 0.1 | 1262 | 1477 | 1,2,3 |
33 | 45.520 | Sibirene | t | 0.7 | 1294 | 1,2 | |
34 | 46.066 | Caryophyllene | 0.2 | 1296 | 1607 | 1,2,3 | |
35 | 50.831 | α-Guaiene | 0.2 | 0.3 | 1372 | 1583 | 1,2 |
36 | 52.204 | Cycloisolongifol-5-ol <trans> | 0.2 | 1395 | 1,2 | ||
37 | 56.184 | Globulol | 1.9 | 1457 | 2095 | 1,2 | |
Total | 98.1 | 97.7 | |||||
Monoterpene hydrocarbons | 17.1 | 15.4 | |||||
Oxygenated monoterpenes | 80.3 | 79.1 | |||||
Sesquiterpenes hydrocarbons | 0.7 | 1.1 | |||||
Oxygenated sesquiterpenes | 2.1 |
a, b The Kovats retention indices determined relative to a series of n-alkanes (C10–C35) on the apolar HP-5 MS and the polar HP Innowax capillary columns, respectively; c identification method: 1 = comparison of the Kovats retention indices with published data, 2 = comparison of mass spectra with those listed in the NIST 02 and Wiley 275 libraries and with published data, and 3 = coinjection with authentic compounds; t = trace (<0.1%).