Table 3.
Sugars | Compounds (δC) | ||||
---|---|---|---|---|---|
1 a | 2 a | 3 b | 4 b | 5 a | |
Ara(p) | |||||
1 | 101.16 | 101.13 | 101.32 | 101.37 | 101.62 |
2 | 74.58 | 74.56 | 71.22 | 71.11 | 74.40 |
3 | 80.45 | 85.25 | 74.60 | 75.98 | 70.67 |
4 | 85.29 | 70.52 | 76.16 | 75.62 | 85.51 |
5 | 67.04 | 67.03 | 67.93 | 67.75 | 67.21 |
Xyl | |||||
1 | 106.47 | 106.44 | 106.44 | ||
2 | 74.91 | 74.89 | 74.88 | ||
3 | 78.04 | 78.01 | 78.07 | ||
4 | 70.54 | 70.78 | 71.19 | ||
5 | 67.04 | 67.03 | 67.02 | ||
Rha | |||||
1 | 101.60 | 101.58 | 98.43 | 98.99 | 101.78 |
2 | 71.99 | 71.98 | 73.46 | 73.87 | 72.39 |
3 | 74.58 | 80.45 | 75.74 | 77.91 | 72.17 |
4 | 73.05 | 73.04 | 74.65 | 73.46 | 74.29 |
5 | 69.84 | 69.86 | 67.34 | 69.81 | 69.83 |
6 | 18.72 | 18.71 | 18.25 | 18.58 | 18.65 |
2-acetyl | |||||
1 | − | − | 171.96 | 172.11 | |
2 | − | − | 21.02 | 21.09 | |
4-acetyl | |||||
1 | − | − | 172.29 | − | |
2 | − | − | 21.15 | − | |
Api | |||||
1 | 112.17 | 112.15 | 112.54 | 112.37 | |
2 | 78.23 | 78.28 | 78.49 | 78.34 | |
3 | 80.49 | 80.48 | 80.68 | 80.71 | |
4 | 75.18 | 75.17 | 75.41 | 75.35 | |
5 | 65.56 | 65.58 | 65.56 | 65.77 |
a Tested in 13C-NMR (125 Hz); b tested in 13C-NMR (201 Hz).