Table 3.
Summary of the most important catalysts used for catalytic combustion of VOCs.
Catalyst | Synthesis Technique | BET Surface Area (m2 g−1) | VOC | GHSV (mL g−1 h−1) |
VOC Concentration | T50b (°C) | Ref. |
---|---|---|---|---|---|---|---|
Ce0.75Zr0.25O2 | sol–gel | 108.4 | methane | 60,000 | 2% | 545 | [150] |
5 wt% Cu/CeO2 | hydrothermal | 22.6 | methane | 27,000 | 1% | 540 | [95] |
1 wt% Cu/CeO2 | thermal decomposition | 68.7 | methane | 54,000 | 1% | 540 | [95] |
Ce0.85Cu0.1Ca0.05O2−δ | citric acid complexation combustion | 31.3 | methane | 30,000 | 1% | 478 | [151] |
Ce(0.6)-La-O | sol–gel | 52.4 | methane | 13,500 | 0.2% | 505 | [152] |
Co3O4-CeO2 | coprecipitation | 31 | methane | 60,000 | 0.3% | 471 | [153] |
2 wt% Pt/Ce0.67Zr0:33O2 | impregnation | 79 | methane | 12,800 | 1% | 550 | [154] |
CeO2 | sol–gel | 3 | toluene | 200,000 | 1000 ppm | 430 | [147] |
5 wt% CeO2/Al2O3 | impregnation | 156 | toluene | 54,000 | 1400 ppm | 275 | [155] |
Ce0.9Zr0.1O2 | sol–gel | 56 | toluene | 20,000 | 1000 ppm | 221 | [156] |
Ce0.9Zr0.1O2 | sol–gel | 56 | ethanol | 20,000 | 1000 ppm | 207 | [156] |
CuO-CeO2/γ-Al2O3 | impregnation | 156 | propane | 2300 | 5.9% | 350 | [157] |
Cu0.13Ce0.87O2 | combustion | 27 | acetone | 60,000 | 1000 ppm | 200 | [158] |
MnOx-CeO2 | sol–gel | 22.2 | formaldehyde | 60,000 | 580 ppm | 160 | [159] |
MnOx-CeO2 | modified coprecipitation | 124 | benzene | 30,000 | 200 ppm | 260 | [159] |
3 wt% Ag/MnOx-CeO2 | deposition precipitation | 124.0 | formaldehyde | 30,000 | 580 ppm | 70 | [160] |
0.5 wt% Pt/CeO2 | impregnation | 3 | toluene | 200,000 | 1000 ppm | 180 | [147] |
1.5 wt% Au/CeO2 | deposition precipitation | 79 | propene | 35,000 | 1000 ppm | 230 | [161] |
0.25 wt% Pt/23wt% CeO2/Al2O3 | sol–gel | 95 | acetic acid | 30,000 | 1000 ppm | 175 | [162] |