Table 2.
Composition of lignin obtained with each organosolv pretreatment. Weight average (MW), number-average (Mn), and polydispersity index (PDI) of acid-insoluble lignin from birch sawdust were determined after acetobromination.
Code | Cellulose (%) | Hemicellulose (%) | Klason Lignin (%) | Ash (%) | MW (g/mol) | Mn (g/mol) | PDI |
---|---|---|---|---|---|---|---|
B0A5a | 0.08 | 1.85 | 95.18 | 0.47 | 4500 | 1200 | 3.75 |
B0A6a | 0.14 | 2.32 | 83.86 | 0.27 | 8000 | 1100 | 7.34 |
B0A6c | 0.50 | 0.32 | 86.44 | 0.42 | 9700 | 1400 | 6.97 |
B0B5a | 0.39 | 1.56 | 92.00 | 0.72 | 11300 | 1400 | 8.21 |
B0B6a | 0.00 | 2.01 | 91.90 | 0.31 | 13300 | 1700 | 8.04 |
B1A5a | 0.14 | 3.55 | 77.93 | 0.12 | 1800 | 800 | 2.28 |
B1A6a | 0.18 | 7.04 | 74.27 | 0.21 | 4500 | 1200 | 3.87 |
B1B5a | 0.10 | 2.48 | 83.08 | 0.11 | 4600 | 1200 | 3.88 |
B1B6a | 0.11 | 3.25 | 89.05 | 0.08 | 15900 | 1900 | 8.53 |
Representation of the codes: 0—pretreatment at 200 °C; 1—pretreatment at 180 °C; A—pretreatment time of 15 min; B—pretreatment of 30 min; 5—50% v/v ethanol content; 6—60% v/v ethanol content; a—no catalyst added; c—1% w/wbiomass H2SO4.