Table 9.
Results of alkaloids identified via HPLC/ESI-QTOF-MS present in fractions 1–7 obtained from experiment 3 via VLC using silanized silica gel as a sorbent from L. clavatum extract.
| Isolated Compounds | Fraction Number | ||||||
|---|---|---|---|---|---|---|---|
| 1 | 2 | 3 | 4 | 5 | 6 | 7 | |
| Acetylfawcettiine | 12.1 | - | - | - | - | 1.2 | 4.9 |
| Lycopodine N-oxide | 12.3 | 8.4 | 6.7 | 3.7 | 2.2 | - | - |
| Lycopodine | 9.7 | 7.3 | 6.5 | 6.2 | 2.2 | 4.3 | 12.6 |
| Dihydrolycopodine | 4.3 | 4.6 | 5.3 | 6.4 | 5.0 | 5.1 | 7.3 |
| Flabelline | - | 0.8 | 1.4 | - | - | - | - |
| Fawcettimine | - | 1.8 | 3.6 | 2.6 | 2.7 | 2.2 | 1.5 |
| 8β-Hydroxylycoposerramine K | - | 2.4 | 3.6 | 2.8 | 1.5 | 1.9 | - |
| Lycoposerramine K | 2.9 | - | - | - | - | - | - |
| 4,6α-Dihydroxylycopodine or epimer | - | - | - | - | - | 1.1 | 1.4 |
| α-Lofoline or epimer | 2.1 | 3.1 | 2.4 | 2.3 | 1.1 | - | 1.8 |
| Deacetylfawcettiine | - | - | 1.8 | 2.0 | 3.7 | 4.7 | 2.5 |
| Serratezomine E | - | 8.1 | 6.2 | - | 2.3 | - | - |
| Japonicumin B or lycoclavanin | 0.3 | 4.2 | 4.1 | - | 4.2 | - | 2.6 |
| 16-Oxolyclanitin | 1.2 | 5.3 | 1.9 | - | - | 2.1 | |
| Unidentified 474.3794 C27H48N5O2 or C26H52NO6 |
- | - | - | - | - | - | 7.2 |
| Unidentified 371.2290 C17H31N4O5 or C19H33NO6 |
9.9 | 8.0 | 9.0 | 10.6 | 4.0 | 9.8 | - |
| Unidentified 415.2532 C19H35N4O6 |
10.5 | 8.4 | 9.6 | 11.3 | 4.2 | 10.1 | 5.5 |
| Unidentified 679.5133 C40H71O8 or C41H67N4O4 |
7.39 | 6.7 | 6.87 | 7.12 | 4.75 | 8.17 | 3.91 |
| % SUM | 71.43 | 64.95 | 72.29 | 56.76 | 37.64 | 48.59 | 53.24 |