Table 2.
Phenolic Compounds |
Contents (mg/L) | ||||||
---|---|---|---|---|---|---|---|
0 h | 12 h | 24 h | 36 h | 48 h | 60 h | ||
Chlorogenic acid | Fermented | 15.05 ± 0.01 ab | 15.27 ± 0.15 ab | 12.30 ± 0.05 c | 13.18 ± 1.03 abc | 15.57 ± 3.12 a | 13.68 ± 0.04 abc |
Control | 15.05 ± 0.01 ab | 13.14 ± 0.03 abc | 13.37 ± 0.75 abc | 12.81 ± 0.12 bc | 14.48 ± 0.62 abc | 14.12 ± 0.07 abc | |
Neochlorogenic acid | Fermented | 17.19 ± 0.02 a | 14.17 ± 1.22 d | 12.91 ± 0.10 e | 1.93 ± 0.07 f | 1.21 ± 0.11 f | 1.28 ± 0.91 f |
Control | 17.19 ± 0.02 a | 15.91 ± 0.21 b | 15.66 ± 0.60 bc | 14.57 ± 0.23 cd | 14.86 ± 0.05 bcd | 15.62 ± 0.02 bc | |
Cryptochlorogenic acid | Fermented | 81.86 ± 0.92 a | 68.12 ± 1.04 b | 64.33 ± 0.05 b | 56.67 ± 2.70 c | 47.16 ± 1.08 d | 50.16 ± 1.55 d |
Control | 81.86 ± 0.92 a | 66.94 ± 0.79 b | 58.53 ± 7.76 c | 28.15 ± 0.44 e | 29.29 ± 1.04 e | 33.81 ± 0.87 e | |
Ferulic acid | Fermented | 208.67 ± 0.16 c | 207.39 ± 0.06 c | 227.06 ± 1.68 b | 226.95 ± 0.11 b | 229.59 ± 0.39 ab | 231.78 ± 1.15 a |
Control | 208.67 ± 0.16 c | 197.00 ± 3.80 e | 204.65 ± 3.53 cd | 207.48 ± 1.39 c | 189.00 ± 3.15 f | 202.11 ± 0.49 d | |
Syringate | Fermented | 5.01 ± 0.01 cd | 4.88 ± 0.12 e | 5.50 ± 0.03 b | 5.84 ± 0.03 a | 5.74 ± 0.08 a | 5.84 ± 0.03 a |
Control | 5.01 ± 0.01 cd | 5.02 ± 0.04 c | 5.03 ± 0.04 c | 4.90 ± 0.01 de | 4.85 ± 0.01 e | 5.00 ± 0.00 cd | |
p-Coumaric acid | Fermented | 19.16 ± 0.01 d | 18.55 ± 0.12 e | 20.78 ± 0.03 b | 20.82 ± 0.01 b | 19.54 ± 0.14 c | 21.33 ± 0.07 a |
Control | 19.16 ± 0.01 d | 19.11 ± 0.19 d | 19.11 ± 0.10 d | 19.64 ± 0.39 c | 18.60 ± 0.10 e | 18.58 ± 0.09 e | |
Gallic acid | Fermented | 12.66 ± 0.10 f | 42.88 ± 1.42 a | 23.78 ± 0.79 d | 21.59 ± 0.37 de | 21.71 ± 0.97 de | 19.87 ± 0.29 e |
Control | 12.66 ± 0.10 f | 22.57 ± 0.73 d | 23.90 ± 2.81 d | 29.55 ± 0.60 bc | 28.87 ± 0.61 c | 31.73 ± 1.01 b | |
Caffeic acid | Fermented | 1.95 ± 0.02 abc | 1.95 ± 0.13 abc | 1.82 ± 0.11 cd | 1.87 ± 0.02 bc | 1.62 ± 0.05 d | 1.96 ± 0.03 abc |
Control | 1.95 ± 0.02 abc | 2.16 ± 0.01 a | 2.19 ± 0.02 a | 2.09 ± 0.04 ab | 2.08 ± 0.01 ab | 1.86 ± 0.26 bc | |
p-Hydroxybenzoic acid | Fermented | 14.35 ± 0.13 ab | 13.25 ± 0.94 b | 5.83 ± 0.02 ef | 8.29 ± 0.47 cd | 15.30 ± 0.37 a | 14.73 ± 0.05 ab |
Control | 14.35 ± 0.13 ab | 7.23 ± 0.07 de | 5.37 ± 1.64 f | 6.35 ± 0.06 ef | 9.58 ± 0.40 c | 14.46 ± 0.15 c | |
Erucic acid | Fermented | 157.36 ± 0.47 a | 146.61 ± 5.50 ab | 127.42 ± 2.59 cd | 127.28 ± 0.31 cd | 133.26 ± 1.65 bcd | 145.76 ± 0.17 ab |
Control | 157.36 ± 0.47 a | 137.53 ± 15.42 bc | 141.37 ± 2.61 bc | 144.04 ± 1.50 ab | 121.34 ± 1.20 d | 136.23 ± 13.31 bcd | |
Catechin | Fermented | 39.01 ± 0.13 a | 34.95 ± 0.45 bc | 22.56 ± 0.16 e | 38.35 ± 1.87 a | 35.75 ± 0.45 b | 38.70 ± 0.00 a |
Control | 39.01 ± 0.13 a | 33.23 ± 0.04 c | 29.87 ± 2.24 d | 30.83 ± 0.20 d | 35.75 ± 0.49 b | 21.33 ± 0.52 e | |
Epicatechin | Fermented | 26.76 ± 0.75 h | 29.39 ± 0.08 d | 29.94 ± 0.00 cd | 32.27 ± 0.04 a | 30.42 ± 0.69 c | 31.40 ± 0.07 b |
Control | 26.76 ± 0.75 h | 28.87 ± 0.14 ef | 28.42 ± 0.49 e | 27.38 ± 0.43 gh | 27.44 ± 0.06 fgh | 27.80 ± 0.29 efg | |
Rutin | Fermented | 13.96 ± 0.05 d | 13.88 ± 0.19 d | 23.12 ± 0.60 a | 16.43 ± 0.02 c | 18.13 ± 0.20 b | 18.87 ± 0.28 b |
Control | 13.96 ± 0.05 d | 13.49 ± 0.35 de | 12.83 ± 0.18 f | 12.42 ± 0.08 f | 12.77 ± 0.40 f | 12.92 ± 0.18 ef | |
Arbutin | Fermented | 17.73 ± 0.38 c | 16.74 ± 3.01 c | 44.07 ± 0.54 a | 46.53 ± 0.06 a | 43.26 ± 4.14 ab | 38.49 ± 0.09 b |
Control | 17.73 ± 0.38 c | 13.51 ± 0.04 c | 17.44 ± 3.97 c | 17.22 ± 2.14 c | 17.20 ± 3.52 c | 15.50 ± 0.85 c | |
Hesperidin | Fermented | 85.77 ± 0.03 fg | 92.30 ± 0.02 efg | 159.28 ± 0.37 b | 194.74 ± 0.85 a | 125.98 ± 0.94 d | 98.49 ± 0.28 e |
Control | 85.77 ± 0.03 fg | 54.08 ± 4.60 h | 135.76 ± 9.80 c | 166.61 ± 4.51 b | 84.38 ± 5.76 g | 94.91 ± 2.78 ef | |
Hesperetin | Fermented | 26.94 ± 0.30 bcd | 29.37 ± 0.16 abc | 32.18 ± 2.81 ab | 29.28 ± 0.76 abc | 33.20 ± 1.14 a | 29.21 ± 1.28 abc |
Control | 26.94 ± 0.30 bcd | 24.69 ± 3.60 cd | 23.56 ± 3.06 cd | 24.42 ± 1.73 cd | 21.39 ± 3.90 d | 21.59 ± 3.60 d | |
Naringin | Fermented | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. |
Control | n.d. | n.d. | n.d. | n.d. | n.d. | n.d. | |
Hyperoside | Fermented | 13.15 ± 0.07 ab | 13.58 ± 0.76 ab | 14.06 ± 0.29 a | 12.99 ± 0.65 ab | 9.97 ± 1.65 ab | 10.46 ± 0.18 ab |
Control | 13.15 ± 0.07 ab | 11.98 ± 1.73 ab | 13.50 ± 3.34 ab | 11.33 ± 0.68 ab | 9.38 ± 0.74 b | 10.44 ± 0.92 ab | |
Quercetin | Fermented | 6.10 ± 0.39 a | 3.76 ± 0.10 c | 4.96 ± 0.32 b | 5.01 ± 0.10 b | 6.12 ± 0.24 a | 6.16 ± 0.28 a |
Control | 6.10 ± 0.39 a | 4.95 ± 0.12 b | 4.87 ± 0.11 b | 4.91 ± 0.27 b | 4.72 ± 0.15 b | 4.76 ± 0.18 b | |
Luteolin | Fermented | 4.27 ± 0.04 cd | 4.11 ± 0.05 cd | 4.69 ± 0.84 bcd | 4.63 ± 1.52 bcd | 5.85 ± 0.03 b | 9.71 ± 0.15 a |
Control | 4.27 ± 0.04 cd | 3.78 ± 0.07 cd | 4.71 ± 0.10 bcd | 4.27 ± 0.00 d | 3.83 ± 0.07 cd | 4.92 ± 0.02 bc | |
Baicalein | Fermented | 3.87 ± 0.28 ab | 4.16 ± 0.11 a | 4.43 ± 0.25 a | 4.54 ± 0.04 a | 4.02 ± 0.00 ab | 4.53 ± 0.10 a |
Control | 3.87 ± 0.28 ab | 3.92 ± 0.61 ab | 4.01 ± 0.32 ab | 2.31 ± 0.02 c | 3.16 ± 0.84 bc | 2.45 ± 0.64 c |
n.d.—not detected. Values are given as the mean ± standard deviation (n = 3), and values marked with different superscript lowercase letters (a–h) within the different periods (0 h–60 h) indicate each compound between the fermented and control are significantly different (p < 0.05).