. Author manuscript; available in PMC: 2022 Apr 21.

Published in final edited form as: J Am Chem Soc. 2021 Apr 8;143(15):5622–5628. doi: 10.1021/jacs.1c00886

Table 2.

Scope, generality, and chemoselectivity of catalytic, atom transfer, cross-aza-pinacol coupling

^a.

0.2 mmol inline, aldehyde (3 eq), AcI (2.6 eq), 5% Mn₂(CO)₁₀, Zn (2 eq), Cy₂NMe (5 eq), CH₂Cl₂, (1 mL), 2 x 23W white CFL, 24 h.

^b.

10% Mn₂(CO)₁₀.

^c.

iPr₂NEt instead of Cy₂NMe.

with Hantzsch ester (0.75 eq). See SI for full details.