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The intramolecular H-bond donor strength in a series of [MnIIIH3bpuea-R(O)]2− complexes is modulated remotely by the R-group, which affects the basicity of the complex and the reaction rate towards 9,10-dihydroanthracene. The experimentally determined second order rate constant k2 was corrected to k to account for 4 equivalents of C─H bonds that can possibly be cleaved in DHA.
