Catalyst, ligand and additive screen for the DaPdNP catalysed Suzuki Miyaura reaction^a.

Entry	Catalyst	Ligand	Additive	Yield (% ±SD)
1	DaPdNP	—	—	34
2	DaPdNP	PPh3	—	24
3	DaPdNP	JohnPhos	—	38
4	DaPdNP	SPhos	—	33
5	DaPdNP	XPhos	—	40
6	DaPdNP	sSPhos	—	6
7	DaPdNP	AmPyol	—	19
8	DaPdNP	TMG	—	62
9	DaPdNP	—	Green tea polyphenols	26
10b	DaPdNP	—	—	0
11	cPdNP	—	—	<1
12	cPdNP	XPhos	—	<1
13	cPdNP	TMG	—	<1
14	Pd/C	—	—	<1
15	Pd/C	XPhos	—	2
16	Pd/C	TMG	—	5
17	DaPdNP	—	TPGS-750-Mc	75
18	DaPdNP	—	TPGS-1000c	>99

^aReactions were performed using 1 (25 mM), 2 (30 mM), K₂CO₃ (30 mM), Pd catalyst (0.25 mM) and ligand (2.5 mM) in sealed tubes under an atmosphere of air. Product concentrations were determined by ¹H NMR spectroscopy relative to an internal standard of TMB. All data shown is an average of three experiments to one standard deviation.

^bPolymer-supported iodobenzoic acid was used.

^c2% w/vol.