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A series of phosphine‐functionalized N‐donor ligand systems, applicable for the construction of metal complexes: (a) phosphorus guanidine,[ 11 , 21 , 22 ] (b) ß‐diketimine, [10] (c) [12] and (d) amidines. The introduction of additional phosphorous containing moieties into the respective ligand scaffold enables the formation of specific pockets and coordination motifs.
