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. 2021 Sep 8;27(57):14287–14298. doi: 10.1002/chem.202102451

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© 2021 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH

This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.

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Part of the ¹⁹F NMR (bottom) and the ¹⁹F{¹H} NMR spectrum (top) of cis‐[Pt(2‐C₉H₈N){κ ²‐(P,N)‐iPr₂ P(C₉H₇ N)}{iPr₂PF}] (6) revealing coupling constants of ¹ J(F,P)= 854. Hz, ³ J(F,P)=59.6 Hz, ³ J(F,H)=14.1 Hz and ² J(F,Pt)=401 Hz.