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. 2021 Sep 8;27(57):14287–14298. doi: 10.1002/chem.202102451

Scheme 2.

Scheme 2

Formation of the Pt(ii) fluorido complex cis‐[PtF{κ 2‐(P,N)‐iPr2 P(C9H7 N)}{iPr2P(C9H8N)}] ⋅ (HF)4 (5 ⋅ (HF)4), its reactivity towards CsF, CO and the rearrangement reaction to the fluorophosphine complex cis‐[Pt(2‐C9H8N){κ 2‐(P,N)‐iPr2 P(C9H7 N)}{iPr2PF}] (6).