The calculated (Cal) and experimentally (Exp) measured reduction potentials vs. Li⁺/Li^(s) of Li⁺ coordinated solvents, in Volt. The parentheses with a minor sign denote the reduced molecule.

Reduction reaction	Potential (V vs. Li+/Li)
	Cal	Exp
Li+-EMC + e− → Li+-(EMC)−	0.45	0.45 (ref. 61)
Li+-EC + e− → Li+-(EC)−	0.62	0.75 (ref. 76)
Li+-(EC)3(EMC)3 + e− → Li+-(EC)−(EC)2(EMC)3	0.64
Li+-FEC + e− → Li+-(FEC)−	0.97	1.1 (ref. 77)
Li+-(EC)2(EMC)3(FEC) + e− → Li+-(EC)2(EMC)3(FEC)−	0.99