Table 2.
Molecular species | RT (min) | Detected m/z, [M–H]– | Error (ppm) | Fragment ions for assignment (m/z) |
---|---|---|---|---|
Strictinin | 5.4 | 633.0765 | +5.1 | 481.0627, 463.0477, 300.9995, 275.0190 |
Pedunculagin or its isomers | 3.6 4.7 |
783.0629 783.0629 |
−7.3 −7.3 |
481.0627, 300.9995, 275.0190 481.0550, 300.9995, 275.0190 |
Casuarictin | 6.8 | 935.0822 | +2.8 | 783.0728, 633.0765, 481.0550, 463.0553, 300.9995, 275.0190 |
Unknown ET or its isomers | 8.3 8.4 9.5 |
1085.0743 1085.0743 1085.0743 |
−0.6 −0.6 −0.6 |
783.0728, 633.0765, 450.9969 300.9995 783.0728, 631.0582, 450.9895, 300.9995 783.0728, 633.0765, 450.9969, 300.9995 |
Davuriicin M1, or its isomer | 6.7 | 1235.0692 | −0.8 | 933.0591, 631.0582, 469.0069, 314.9822, 300.9995, 298.9870 |
RT: retention time.
Pedunculagin and davuriicin M1 were tentatively identified.