Observed fragments and appearance energies determined by energy-resolved CID of the mass-selected ion [Ru(CYM)(pta)(p-Cl-dkt)(NAC)]+.
Fragment | m/z | Eliminated fragment(s) | AE/eV |
---|---|---|---|
[Ru(pta)(p-Cl-dkt)(NAC)]+ | 671 | CYM | 1.8 ± 0.1 |
[Ru(CYM)(pta)(p-Cl-dkt)]+ | 642 | NAC | 1.8 ± 0.1 |
[Ru(CYM)(pta)(NAC-H)]+ | 555 | (p-Cl-dkt)H | 1.6 ± 0.1 |
[Ru(CYM)(p-Cl-dkt)]+ | 485 | NAC + pta | 2.0 ± 0.1 |
[Ru(CYM)(NAC-H)]+ | 398 | p-Cl-dkt·H + pta | 1.8 ± 0.1 |
[Ru(CYM)((NAC-H)-CH2CO)]+ | 356 | p-Cl-dkt·H + pta + CH2CO | 2.0 ± 0.1 |