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. 2019 Jan 28;48(8):2626–2634. doi: 10.1039/c8dt04350g

Observed fragments and appearance energies determined by energy-resolved CID of the mass-selected ion [Ru(CYM)(pta)(p-Cl-dkt)(NAC)]+.

Fragment m/z Eliminated fragment(s) AE/eV
[Ru(pta)(p-Cl-dkt)(NAC)]+ 671 CYM 1.8 ± 0.1
[Ru(CYM)(pta)(p-Cl-dkt)]+ 642 NAC 1.8 ± 0.1
[Ru(CYM)(pta)(NAC-H)]+ 555 (p-Cl-dkt)H 1.6 ± 0.1
[Ru(CYM)(p-Cl-dkt)]+ 485 NAC + pta 2.0 ± 0.1
[Ru(CYM)(NAC-H)]+ 398 p-Cl-dkt·H + pta 1.8 ± 0.1
[Ru(CYM)((NAC-H)-CH2CO)]+ 356 p-Cl-dkt·H + pta + CH2CO 2.0 ± 0.1