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. 2021 Nov 11;9(46):15451–15460. doi: 10.1021/acssuschemeng.1c04591

Table 2. Maximum Wavelength of Absorption, ENR, and Normalized ENR Values of Traditional Solvents and Their Mixturesa.

solvents λmax ENR ENRN % water
water 585.32 48.85 ± 0.17 1.000  
Lac + Bet + Dec (5:1:0.1) 574.33 49.78 ± 0.05 0.903 ± 0.010 N/D
Thy + Bor (1:1) 562.33 50.84 ± 0.14 0.792 ± 0.010 N/D
Men + Thy (1:1) 561.67 50.90 ± 0.05 0.786 ± 0.010 0.157 ± 0.020
methanol 559.50 51.10 ± 0.05 0.765 ± 0.010 22,265 ± 0.210
Lac + Bet + Dec (2:1:0.35) 555.00 51.52 ± 0.09 0.722 ± 0.010 N/D
Men + Thy (2:1) 553.33 51.67 ± 0.11 0.706 ± 0.010 0.127 ± 0.020
Lac + Bet + Dec (2:1:0.25) 553.33 51.67 ± 0.22 0.706 ± 0.020 N/D
ethanol 552.33 51.76 ± 0.14 0.696 ± 0.010 <0.001
isopropanol 549.67 52.02 ± 0.07 0.670 ± 0.010 0.216 ± 0.020
Men + Thy (4:1) 549.00 52.08 ± 0.10 0.663 ± 0.010 0.133 ± 0.010
Men + Mal (8:1) 547.33 52.24 ± 0.11 0.646 ± 0.010 N/D
Men + Thy (8:1) 545.67 52.40 ± 0.06 0.630 ± 0.010 N/D
iso-octane/isopropanol (1:9) 542.00 52.75 ± 0.00 0.593 ± 0.010 0.513 ± 0.120
iso-octane/isopropanol (2:8) 541.67 52.78 ± 0.06 0.589 ± 0.010 N/D
iso-octane/isopropanol (3:7) 541.67 52.78 ± 0.06 0.589 ± 0.010 0.814 ± 0.090
Men + Bor (7:2) 540.33 52.91 ± 0.06 0.576 ± 0.010 0.158 ± 0.030
Men + Lau (4:1) 539.57 52.99 ± 0.07 0.568 ± 0.010 0.166 ± 0.020
acetone 539.50 53.00 ± 0.08 0.567 ± 0.010 <0.2
Men + Lau (8:1) 538.43 53.01 ± 0.07 0.556 ± 0.000 N/D
Men + Dec (2:1) 538.00 53.14 ± 0.00 0.552 ± 0.000 0.203 ± 0.020
Men + Myr (4:1) 537.67 53.18 ± 0.06 0.548 ± 0.010 N/D
iso-octane/iso-propanol (4:6) 537.33 53.21 ± 0.11 0.545 ± 0.010 0.459 ± 0.020
Men + Lau + Dec (4:1:1) 537.00 53.24 ± 0.01 0.542 ± 0.010 0.088 ± 0.010
Men + Dec (7:2) 536.67 53.28 ± 0.11 0.538 ± 0.010 0.140 ± 0.010
Men + Lau (2:1) 535.33 53.41 ± 0.06 0.524 ± 0.010 0.067 ± 0.010
Men + Lau + Dec (2:1:1) 535.00 53.44 ± 0.10 0.521 ± 0.010 0.144 ± 0.020
iso-octane/isopropanol (5:5) 535.00 53.44 ± 0.10 0.521 ± 0.010 0.465 ± 0.020
Men + Dec (1:3) 532.00 53.74 ± 0.00 0.489 ± 0.000 N/D
iso-octane/isopropanol (6:4) 530.67 53.88 ± 0.06 0.475 ± 0.010 0.494 ± 0.140
toluene 526.00 54.36 ± 0.00 0.425 ± 0.000 0.049 ± 0.000
iso-octane/isopropanol (7:3) 525.67 54.39 ± 0.06 0.422 ± 0.010 0.361 ± 0.210
Shellsol A 525.33 54.42 ± 0.06 0.418 ± 0.010 0.112 ± 0.000
xylene 524.67 54.49 ± 0.06 0.411 ± 0.010 0.110 ± 0.000
turpentine 518.67 55.09± 0.06 0.345 ± 0.010 N/D
iso-octane/isopropanol (8:2) 518.00 55.55 ± 0.06 0.300 ± 0.010 0.208 ± 0.190
white spirit (about 16% aromatic) 516.67 55.36 ± 0.03 0.323 ± 0.010 0.051 ± 0.000
iso-octane/isopropanol (9:1) 514.67 55.67 ± 0.06 0.300 ± 0.010 0.168 ± 0.020
Shellsol D40 494.50 57.82 ± 0.15 0.064 ± 0.020 0.008 ± 0.000
Shellsol T (0% aromatic) 494.00 57.88 ± 0.00 0.058 ± 0.000 0.008 ± 0.000
iso-octane 489.33 58.43 ± 0.03 0.000 0.006 ± 0.000
a

N/D—not determined.