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. 2021 Nov 25;5(3):873–921. doi: 10.1007/s42247-021-00319-x

Table 1.

Examples of nanoparticles obtained by green synthesis techniques

Nanoparticles Green synthesis technique Shape Size (nm) Reported applications References
Ag Maltose as reducing agent and soluble starch as stabilizer Spherical with high monodispersity 5 - [174]
Ag Microwave-assisted using orange peel extract Nanospheres 7.36 ± 8.06 - [181]
Ag In vivo synthesis of nanomaterials in plants: Brassica juncea, Festuca rubra, and Medicago sativa Variable Variable - [182]
Ag Using marine algae Caulerpa racemosa Spherical with few triangular nanoparticles 10 nm mean - [183]
Ag Maltose as reductor and cornstarch as stabilizing agent Spherical 5–20 Included in nanocomposite films for dairy product shelf-life extension [184]
Ag Maltose as reductor and different concentrations of cornstarch as stabilizing agent Spherical 13.4–19.9 Included in starch films for food packaging area [185]
Ag Lemon juice as reducing and stabilizing agent Spherical 5.5–13.5 Included in starch-nanocomposite films for packaging area [186]
Au Using citrus fruits aqueous extract: Citrus limon, Citrus reticulata, and Citrus sinensis Various shapes 15–80 - [187]
Au Using brown algae Cystoseira baccata Spherical 8.4 ± 2.2 Anticancer activity [188]
Au Using Lawsoniainermis leaf extract Spherical ∼20 Catalytic activity in the degradation of anthropogenic aromatic pollutants and dyes, like bromophenol blue and methyl red [189]
Au Using an endophytic strain Fusarium solani ATLOY – 8 has been isolated from the plant Chonemorpha fragrans Needle and flower-like structures with spindle shape 40–45 The NPs have shown effective anticancer activities [190]
CoO Complexation and surface passivation with starch Square 15–30 - [191]
Co3O4 Using leaves extract of plant Calotropis gigantea Spherical 50–60 Thermal decomposition of ammonium perchlorate and dye-sensitized solar cells [192]
CoO Using P. granatum extracts Spherical 40–80 Photo-catalytic applications [193]
Co3O4 Walnut green skin extract as reducing and stabilizing agent Spherical 60–80 - [194]
CoO/Co3O4 Rosemary extract Sheet ∼100 - [195]
Cu/Cu2O Synthesized by pulsed laser ablation of copper in water Spherical and are self-assembled forming a cactus-like 2–7 - [196]
Cu Using carboxymethyl cellulose as capping agent Spherical 5.5 ± 0.5 Inclusion on modified electrode and used as electrochemical nitrite sensor [197]
CuO Citric acid mediated synthesis using cinnamon bark extracts Spherical 50–300 Catalytic degradation of dyes and antimicrobial activity [198]
Cu Microwave-mediated green synthesis using Citrus sinensis aqueous fruit extract Round shape 6.93–20.70 - [199]
Fe Using Eucalyptus Tereticornis leaves extract Cubic 40–60 Can be applied as an adsorption − flocculation agent in water purification and contaminated groundwater remediation [200]
Fe3O4 Using Aloe vera extract Cubic Spinel Structure 6–30 - [201]
Fe2O3/Fe3O4 By laser ablation method at different values of energy Spherical and agglomerates 14.9–18.7 - [202]
MgO Using bacteria Cubic 30 Anticancer study [203]
MgO Using Costus pictus D. Don plant leaf extract as a reducing agent Hexagonal ∼50 Antimicrobial and anticancer activity [204]
MnO2 Using fresh lemon juice and peel extract Agglomerates of fine particles with juice and nanorods with peel extract  < 10 nm and nanorods of 8.8 nm Possible application as positive electrode for lithium-ion batteries [205]
TiO2 Using leaf aqueous extract of Solanum trilobatum Uneven spherical and oval 70 Larvicidal and pediculicidal activities [206]
TiO2 Bengal gram beans (Cicer arietinum L.) Spherical ∼14 As anode in lithium-ion battery [207]
TiO2 Using leaf extract of Jatropha curcasL Spherical 13 Photocatalytic degradation of tannery wastewater [208]
TiO2 Using lemon peel extract Spherical 80–140 - [209]
ZnO Zn(NO3)2 as precursor and Cayratia pedata leaves extract as reducing agent Agglomerated form confirmed by FESEM analysis 52.24 - [168]
ZnO Combination of sol–gel with hydrothermal growth, using tetramethylammonium hydroxide as a structure-directing agent Nanorods Width 15 nm, and length 236 nm Incorporated in composite materials [210]
ZnO Laser ablation using a starch solution as controller and stabilizer agent Spherical 6–28 - [211]