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. 2021 Nov 12;11(11):1684. doi: 10.3390/biom11111684

Table 1.

Cellulose/silver nanocomposites: summary of preparation methods, properties, and applications.

Cellulose Source Preparation Method Properties Applications Ref.
Cellulose Chemical reduction Ag/ZnO decorated cellulose nanocomposite Rapid sterilization and eradication [82]
Synthesis of silver nanoparticles-covered three-dimensional cellulose 3D cellulose-Ag scaffold Tissue engineering and other relevant applications [142]
Surface sol−gel method TiO2/Ag nanosponges containing uniform dispersion of silver nanoparticles Photocatalysts [143]
Cellulose fibers In situ biosynthesis of Ag NPs by sumac leaf extract as reducing and stabilising agent Face-centered cubic Ag NPs with size of 52 to 105 nm Ag NP improved the durability of the coating [83]
Cellulose nanofibers Thermal treatment and DMF as reducing agents Good distribution of AgNPs on cellulose nanofibers Antimicrobial activities [77]
Decoration with AgNPs via ultraviolet radiation and copper nanoparticles via chemical reduction The metal release related to the contents of copper or silver Superior bactericidal activity [85]
Directional freeze-drying Silver nanowires Anisotropic 3D composite sponge [144]
Celluose nanocrystals Nucleation of silver nanoparticles Mediators for silver nanoparticles preparation with good size distribution [43]
Cellulose acetate nanofibers In situ synthesis of silver nanoparticles followed by electrospinning technique Dense and compact entangled nanofibers An efficient anticorrosive material [92]
Bacterial cellulose UV light irradiation AgNPs with narrow size distribution along with some aggregate Antimicrobial membrane
for wound-healing treatment
[20]
Hydrogel. In situ reduction of Ag NPs Homogeneous distribution of Ag NPs inside BC hydrogel Broad-spectrum antimicrobial performance [87]
Nanocrystals. Chemical reduction of Ag+ ions High metallic Ag content ranging from 88% to 97% Food packaging, paints, or surface treatment [94]
Silver nanoparticles ~16.5 nm were thermal reduction In situ synthesized on TEMPO oxidized bacterial cellulose nanofiber surfaces by Wound dressing [145]
Oxidized bacterial cellulose Ion-exchange followed by thermal reduction Controlled size distribution [54]
Dicarboxylic cellulose In situ immobilization of silver nanoparticles Uniform silver nanoparticles with 15 nm size. Dicarboxylic cellulose/silver nanocomposite [19]
Oxidized cellulose microfibrils containing aldehyde groups Silver mirror reaction Particle size ranged from
5 to 25 nm
Materials had an electric conductivity of
approximately 5 S/cm
[34]
Dialdehyde
nanofobrillated cellulose
In situ immobilization of silver nanoparticles Silver
nanoparticles (~31.07 nm) were fabricated and
uniformly anchored
Controlled release and long-term antibacterial [146]
Hydroxypropyl cellulose. Silver-coated zinc oxide nanoparticles
by solution blending
Multifunctional composite films Accelerated wound-healing, antibacterial properties [35]
TEMPO-oxidized cellulose nanofibrils Silver nanoparticles diameter range of 8−25 nm In situ reduction to form
CNF/silver nanoparticle
Suspention
Selective detection of cysteine [147]
Cellulose ultrathin films grafted by N,N′-carbonyldiimidazole In situ immobilization of silver nanoparticles Higher silver density regions Enable controlled electrical conductivity of cellulose surfaces [61]
Cellulose pulp Hydrothermal in
situ reduction
followed by
dry-jet wet-spun
Homogenous distributed silver among the fiber cross section Yellow fabrics [76]
Cellulose paper The addition of various cellulose derivatives suppresses aggregation of Ag NPs during reduction The concentration of Ag NPs is proportional to the initial silver salt concentration Enhanced antibacterial activity of the cotton fibers [86]
Dip-coating technique Silver nanowire Cellulose/silver nanowires papers [148]
Filter paper Silver nanoparticles Reduction and immobilization Catalyst for or 4-nitrophenol reduction, and to emphasize its duality as a SERS substrate [149]
Cellulose nanowhiskers Chemical reduction Homogeneous AgNPs Antimicrobial activity and biomedical applications [81]
Electrospun cellulose acetate nanofiber Electrospun nanomats of cellulose acetate with the incorporation of Ag NPs Green synthesized silver nanoparticles (3–8 nm) Activity towards biofilms, healthcare, and design of antimicrobial nanomat and wound dressing [91]
Porous cellulose Ion exchange of carboxylate groups to Ag cations followed by the reduction Composite cellulose/Ag particles Catalysis [78]
Porous cellulose
particles
Solvent-releasing method: silver cation exchange reduction reaction using
the carboxylate groups
Composite
cellulose/Ag particles
Catalysis [124]
Cellulose/Keratin One-Pot Synthesis 27 ± 2 for Ag0 and 9 ± 1 nm for Ag+ Blends containing either Ag+ or Ag0 [65]
Regenerated cellulose Hyperbranched polyamide-amine/silver nanoparticles In situ Food packaging [150]