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. 2021 Nov 10;13(22):3892. doi: 10.3390/polym13223892
A frequency factor in the kinetic model of viscosity reduction [Pa0.3 · s1.3]
Cp heat capacity of resin [J/(kg·K)]
D inner diamenter of the barrel [m]
E activation energy of thermal decomposition [J/mol]
f fill ratio [-]
H height of the screw channel [m]
k reaction rate of thermal decomposition [1/s]
l length of the die [m]
Lp path length of the screw [m]
L/D ratio of total length of screw to inner diameter of barrel in an extruder [-]
n exponent in the Cross model [-]
nN number of polymers with N number of nodes [-]
N screw rotational speed [1/s]
N number of nodes of a linear polymer [-]
N¯ number average degree of polymerization [-]
Nu average Nusselt number [-]
Nuz local Nusselt number at z [-]
p pressure of resin [Pa]
q heat flux [W/m2]
Q flow rate [m3/s]
r radial coordinate of the die [m]
R radius of the die [m]
Rg gas constant = 8.31 J/(mol · K)
S cross-sectional area of the screw channel or die [m2]
t time [s]
T temperature of resin [K]
Tb barrel temperature [K]
Tf exit temperature of the high-shear extruder [K]
Tr reference temperature [K]
Tw temperature of the die [K]
T model parameter of the zero-shear viscosity [K]
vz z-component of the fluid velocity [m/s]
V velocity of the barrel with respect to an observer on the screw [m/s]
Vz z-component of V [m/s]
W width of the screw channel [m]
x coordinate of the channel width direction of the screw [m]
X weight fraction in TGA analysis [-]
y coordinate of the channel depth direction of the screw [m]
z coordinate for down-channel direction or axial direction of the screw [m]
α pressure gradient [Pa/m]
β heating rate in TGA analysis [C/min]
γ˙ shear rate of resin [1/s]
η non-Newtonian viscosity of resin [Pa·s]
η0 zero-shear viscosity in the Cross model [Pa·s]
ηr zero-shear viscosity at Tr [Pa·s]
ηrf value of ηr at the exit of the high-shear extruder [Pa·s]
κ thermal conductivity of resin [W/(m·K)]
ρ melt density of resin [kg/m3]
τ shear stress of resin [Pa]
τ characteristic shear stress in the Cross model [Pa]
ϕ screw angle [rad]