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. 2021 Nov 17;10(11):2489. doi: 10.3390/plants10112489

Table 1.

Chemical composition of the essential oils and hydrolats identified by GC-MS (%).

Nr. Crt. RI Compound Name Class TV
EO
TV
HD
TP
EO
TP
HD
LA
EO
LA
HD
LI
EO
LI
HD
OV
EO
OV
HD
OVA
EO
OVA
HD
1 930 α-Thujene MH 0.89 0.07 0.04 - 0.53 - 0.26 - 0.07 - 0.75 -
2 939 α-Pinene * MH 0.68 - 0.21 - - - 1.31 - 0.17 - 0.31 -
3 954 Camphene MH 0.69 - 0.23 - 0.22 - 0.73 - - - 0.06 -
4 975 Sabinene * MH 0.13 - 0.28 - 0.21 - 0.66 - 16.45 0.44 1.32 0.04
5 979 β-Pinene * MH 0.31 - 2.19 - 0.69 - 1.48 - 0.65 - 1.31 -
6 990 β-Myrcene * MH - - 0.07 - 0.24 - - - - - - -
7 1002 α-Phellandrene * MH - - - - - - 0.13 - - - 0.1 -
8 1003 2-Carene MH - - - - 0.39 - - - - - - -
9 1011 3-Carene * MH - - - - 0.18 - 0.3 - 1.12 - - -
10 1012 (+)-4-Carene MH 0.75 - - - - - 0.13 - 0.08 - 1.4 -
11 1014 α-Terpinene MH - - 0.11 - - - - - - - 0.09 -
12 1020 D-Limonene * MH 0.33 - 0.21 - - - 2.65 0.07 - - - -
13 1021 o-Cymene MH - - - - - - 0.05 - - - - -
14 1023 m-Cymene MH 0.1 - - - 0.08 - 0.36 - 0.07 - - -
15 1024 p-Cymene MH 26.4 2.28 0.07 - - - - 0.16 - 1.09 20.81 2.68
16 1037 cis-β-Ocimene * MH - - 0.16 0.06 1.21 - 4.92 - 0.6 - 2.71 0.17
17 1050 trans-β-Ocimene * MH - - 2.14 - 0.13 - 1.58 - 4.96 - 2.57 -
18 1059 γ-Terpinene MH 3.6 0.12 0.32 - 0.09 0.04 0.44 - 0.35 - 13.73 1.15
19 1088 α- Terpinolen MH 0.05 - 0.07 - - - 0.64 - 0.04 - - 0.07
20 1322 Linalyl propionate MH - - - - 0.6 - - - - - - -
21 Neo-allo-ocimene MH - - - - - - 0.28 - 0.17 - 0.19 -
22 ψ-Limonene MH 0.09 - - - - - 1.56 - - - - -
23 1-Undecene, 4-methyl- MH - - - - - - - - - 0.48 - -
24 873 1-Hexanol MO - - - - - - 0.3 0.64 - - - -
25 878 4-Hexen-1-ol, (Z)- MO - - - - - - - 0.08 - - - -
26 963 3-Octanone MO 2.83 - - - - - - - - 2.82 - -
27 977 1-Octen-3-ol MO 0.87 1.66 0.3 0.44 - - - 0.73 - 13.31 - 1.14
28 978 1-Octen-3-one MO - - - 0.36 - - - - - - - -
29 980 3-Octanol MO 0.9 0.82 - 0.15 - - - - - 2.59 - -
30 1010 Acetic acid, hexyl ester MO - - - - - - 0.14 0.06 - - - -
31 1029 Eucalyptol MO - - 0.37 1.12 9.16 20.8 18.97 24.38 0.15 5.39 - -
32 1070 cis-Sabinene hydrate MO 2.3 0.62 1.58 - 0.45 - - - - - - -
33 1073 cis-Linalool oxide MO - - - - - 1.92 - 0.61 - - - 2.79
34 1089 trans-Linalool oxide MO - - - - - 0.98 - 0.45 - - - 2.18
35 1096 Linalool MO - 0.65 0.6 0.23 16.15 22.47 28.77 29.83 0.23 11.59 26.54 54.09
36 1099 trans-Sabinene hydrate MO 0.44 - - 1.03 - - 0.37 - - 0.97 0.11 1.08
37 1105 Propanoic acid, hexyl ester MO - - - - - - 0.06 - - - - -
38 1130 2-Pinen-7-one MO - - - 0.42 - - - - - - - -
39 1135 Limonene oxide MO - - - - 0.34 0.3 - - - - - -
40 1138 Limonene epoxide MO - - - 0.1 - - - - - - - -
41 1142 cis verbenol MO - - 0.86 - - - - - - - - -
42 1144 trans-Sabinol MO 0.03 - - - - - - 0.09 - - - -
43 1145 trans-Verbenol MO 0.05 - 1.19 - - - - - - - - -
44 1146 Camphor MO 0.04 - 0.46 0.38 4.35 16.94 4.32 9.21 - 1.02 - -
45 1147 Nopinone MO - - - - - - - 0.16 - - - -
46 1148 6-Octenal, 7-methyl-3-methylene- MO - - - 0.54 - - - - - - - -
47 1153 Camphene hydrate MO - - - - - - - 0.05 - - - -
48 1156 Neryl oxide MO - - - 0.14 - - - - - - - -
49 1163 Pinocarvone MO - - - - - - - 0.03 - - - -
50 1165 Isoneral MO - - - 0.7 - - - - - - - -
51 1168 Lavandulol MO - - - - - - 0.65 0.84 - - - -
52 1169 endo-Borneol MO 1.85 2.42 1.58 0.15 3.25 6.55 9.3 13.65 - 1.07 - -
53 1177 Terpinen-4-ol MO 0.17 - 0.25 - 2.83 7.92 5.48 10.45 0.02 4.94 0.2 -
54 1184 Isogeranial MO 0.05 - - 1.33 - - - - - 0.25 - 0.13
55 1188 α-Terpineol MO 0.1 - 0.21 0.1 0.85 4.36 0.95 3.17 0.09 6.16 0.19 -
56 1190 Methyl salicylate MO - - - - - - - - - - 0.13 -
57 1194 Butanoic acid, hexyl ester MO - - - - - - 0.86 - - - - -
58 1199 Estragole MO - - - 0.25 - - - - - - - -
59 1206 cis-Verbenone MO - - 0.16 - - - - 0.05 - - - -
60 1209 trans-Piperitol MO - - - - - - - 0.05 - - - -
61 1227 Citronellol MO - - - 0.28 - - - - - - - -
62 1232 cis-Geraniol MO - - - 2.18 - - 0.07 0.65 - - - -
63 1235 Thymol methyl ether MO 10.78 0.56 - - - - - - 0.28 - - -
64 1237 Butanoic acid, 2-methyl-, hexyl ester MO - - - - - - 0.39 - - - - -
65 1239 β-Citral MO - - 20.3 27.7 - - - - - - - -
66 1241 Isobornyl formate MO - - - - 0.07 - - - - - - -
67 1244 Carvacrol methyl ether MO 6.26 1.64 - - - - - - - - 3.04 0.97
68 1246 D-Carvone MO - - - - - - - 0.15 - 0.18 - -
69 1252 (-)-cis-Myrtanol MO - - - 0.31 - - - - - - - -
70 1254 Geraniol MO - - - 2.03 - - - - - - - -
71 1255 Piperitone MO - - - 0.12 - - 0.04 0.1 - - - -
72 1258 Linalyl acetate MO - - - 0.28 36.7 5.69 3.73 0.19 0.55 - - -
73 1264 (-)-trans-Myrtanol MO - - 0.17 - - - - - - - - -
74 1268 Geranial MO - - 20.66 37.91 - - - - - - - -
75 1287 Bornyl acetate MO - 0.36 0.2 - - - 0.29 0.07 - - - -
76 1290 Thymol MO 15.52 62.96 9.7 - - - - - 0.21 1.92 6.88 21.96
77 1292 Lavandulyl acetate MO - - - 1.99 3.14 0.81 0.99 - - - - -
78 1299 Carvacrol * MO 1.85 21.48 0.34 - - - - - 0.08 0.43 - 0.45
79 1333 Hexyl tiglate MO - - - - - - 0.15 - - - - -
80 1352 Thymol acetate MO 0.05 - - - - - - - - - - -
81 1381 Nerol acetate MO - - 3.33 3.24 0.14 0.19 0.11 - - - - -
82 1384 Hexanoic acid, hexyl ester MO - - - - - - 0.19 - - - - -
83 1435 Coumarin MO - - - - - 1.54 - 0.13 - - - -
84 α-Limonene diepoxide MO - - - - - 1.63 - - - - - -
85 cis-p-Mentha-2-en-1-ol MO - - - - - - 0.07 0.15 - - - -
86 Linalyl formate MO - - - - - 0.09 0.09 - - - - -
87 trans-Pyranoid linalool oxide MO - - - - - - - 0.07 - - - -
88 n-Hexyl butanoate MO - - - - - - - 0.05 - - - -
89 (-)-trans-Isopiperitenol MO - - - - - - - 0.04 - - - -
90 2-Caren-4-ol MO - - - - - - 0.05 0.13 - - - -
91 Cumic aldehyde MO - - - - - - 0.47 0.25 - - - -
92 p-Cymen-7-ol MO 0.14 - - - - - 0.12 0.23 - - - -
93 Car-3-en-5-one MO - - - 0.12 - 0.32 - 0.07 - - - -
94 p-Cymen-8-ol MO 0.08 - - - - - - - - - - 0.9
95 8,9-Dehydrothymol methyl ether MO 0.17 - - - - - - - - - - -
96 3-Carene-2,5-dione MO 7.9 - - - - - - - - - - -
97 2,4-Di-tert-butylphenol MO - 0.51 - - - - - - - - - -
98 1-Nonen-3-ol MO - - - 0.12 - - - - - 0.99 - -
99 Rosefuran MO - - - 0.05 - - - - - - 0.03 -
100 p-Menth-1-en-7-al MO - - - 0.31 - - - - - - - -
101 p-Menth-3-en-9-ol MO - - - 0.36 - - - - - - - -
102 trans-3(10)-Caren-2-ol MO - - - 0.29 - - - - - - - -
103 Hydroxy-α-terpenyl acetate MO - - - 0.12 - - - - - - - -
104 Isothymol methyl ether MO - - - - - - - - 0.02 - - -
105 Dihydroedulan MO - - - - - - - - 0.12 0.28 0.26 0.71
106 cis-p-2-Menthen-1-ol MO - - - - - - - - - 0.45 - -
107 3-p-Menthen-7-al MO - - - - - - - - - 0.17 - -
108 2,4-Di-tert-butylphenol MO - - - - - - - - - 1.1 - -
109 Limonene diepoxide MO 0.02 - - 0.3 - - - - - - - -
110 p-Cymen-8-ol MO - - - - - - - - - - - -
111 1376 α-Copaene SH 0.05 0.07 - - - - - - 0.15 - 0.26 -
112 1378 isoledene SH 0.14 - - - 0.25 - 0.03 - - - 0.43 -
113 1389 (-)-β-Bourbonene SH 0.29 - 1.22 0.3 - - - - 1.65 0.47 0.52 -
114 1391 β-Elemen SH - - 0.57 0.16 - - - - 0.51 - 0.21 -
115 1402 Sesquithujene SH - - - - - - 0.07 - - - - -
116 1405 β-Longipinene SH 0.03 - - - - - - - - - - -
117 1408 Isocaryophyllene SH - - 0.24 1.49 2.16 - 2.26 - 13.41 - 3.04 -
118 1414 cis-α-Bergamotene SH 0.03 - 0.03 - 0.29 - 0.08 - 1 - 0.11 -
119 1419 β-Caryophyllene * SH 3.14 0.64 0.96 - 2.69 0.22 0.46 - - 0.32 0.98 0.23
120 1422 β-Cedrene SH 0.1 - - - 0.55 0.08 0.04 - - - - -
121 1432 β-Copaene SH 0.15 - 0.12 0.08 - - - - 0.72 - 0.19 -
122 1440 α-Guaiene SH 0.04 - - - - - - - - - 0.46 -
123 1441 Aromandendrene SH 4.4 0.86 1.97 0.06 - - - - - - - 1.12
124 1444 β-Farnesene SH - - 0.32 - - - - - - - - -
125 1447 Isogermacrene D SH - - 0.42 - - - - - - - - -
126 1454 Humulene SH 0.13 - - - - - - - 3.08 - 0.22 -
127 1456 trans-α-Bergamotene SH - - - - - - - - 0.19 - - -
128 1459 γ-Elemene SH - - - - - - - - 0.37 - - -
129 1468 cis-Muurola-4(15),5-diene SH - - - - - - - - 1.16 - - -
130 1479 γ-Muurolene SH 0.16 - 0.31 - - - 0.07 - 0.19 - 0.11 -
131 1481 Germacrene D SH 1.03 0.28 15.34 3.67 2.49 0.23 0.13 - 22.63 - 5.98 2.59
132 1498 Valencene SH 0.05 - - - - - - - - - 0.16 -
133 1502 Bicyclogermacrene SH - - - 0.21 - - - - 5.18 - 0.56 -
134 1507 α-Farnesene SH - - 0.34 - 0.14 - 0.1 - 15.64 - - -
135 1509 α-Bisabolene SH - - 0.04 0.12 0.35 0.07 - - 2.22 - 0.13 -
136 1512 γ-Cadinene SH 0.14 - - - 0.92 0.19 0.02 - 0.58 - 0.16 0.58
137 1523 β-Sesquiphellandrene SH - - - 0.15 - - - - - - - -
138 1544 Nerolidol SH - - - - - 0.23 - - - 0.25 - -
139 Cadina-3,5-diene SH - - - - - - - - 0.52 - - -
140 1513 (R)-lavandulyl (R)-2-methylbutanoate SO - - - - - - 0.33 - - - - -
141 1561 Nerolidol SO - - - 1.04 - - - - - - - -
142 1562 Elemol SO - - 0.6 4.32 - - - - - - - -
143 1580 Germacren D-4-ol SO - - 0.19 - - - - - 2.97 - - -
144 1582 (-)-Spathulenol SO 0.29 - - 0.1 - - - - - 5.64 0.73 1.55
145 1583 Caryophyllene oxide SO 1.4 0.06 - - 0.4 0.25 0.1 - - 12.44 0.67 0.73
146 1615 Humulene oxide SO 0.03 - - - - - - - - - 0.27 -
147 1631 γ-Eudesmol SO - - - 0.19 - - - - - - - -
148 1632 Epicubenol SO - - - - 0.12 0.11 - - 0.23 0.68 - -
149 1640 τ-Cadinol SO - - - - 2.45 1.84 - - 0.47 2.86 0.26 0.39
150 1641 Alloaromadendrene oxide-(1) SO - - - - - - - - - 0.4 0.1 -
151 1642 τ-Muurolol SO 0.06 - - - - - - - 0.21 - 0.16 0.37
152 1644 Aromadendrene oxide-(2) SO 0.06 - - - - - - - - 0.4 - -
153 1648 α-Muurolol SO - - - - - - - - - 1.19 - -
154 1654 α-Eudesmol SO - - - 0.4 - - - - - - - -
155 1682 Nerolidyl acetate SO - - 8.03 - - - - - - - - -
156 1687 α-Bisabolol SO - - - - 3.48 2.26 0.65 - 0.33 - - -
157 1692 Shyobunol SO - - - - 0.46 - - - - - 0.99 0.91
158 1696 Farnesol SO - - - 0.08 - - - - - - - -
159 1762 cis-Lanceol SO 0.17 - - - - - - - - - - -
160 1765 15-Hydroxy-α-muurolene SO 0.07 - - - - - - - - - - -
161 Aromadendrane-4,10-diol SO - - - - - - - - - 0.42 - -
Total unidentified (%) 1.57 1.94 0.87 2.34 1.25 1.97 1.25 2.96 0.07 17.29 0.57 1.02
Total identified (%) 98.43 98.06 99.13 99.68 98.75 98.03 98.75 97.09 99.93 83.21 99.49 98.98
Total of Major Compounds (%)
Monoterpene hydrocarbonates (MH) 34.02 2.47 6.1 0.06 4.57 0.04 17.48 0.23 24.73 2.01 45.35 4.11
Monoterpenes oxygenate (MO) 52.4 93.68 62.26 85.15 77.43 92.51 76.93 96.81 1.75 55.63 37.38 86.4
Total Monoterpene 86.42 96.15 68.36 85.21 82 92.55 94.41 97.03 26.48 57.64 82.73 90.51
Sesquiterpene hydrocarbonates (SH) 9.88 1.85 21.88 6.24 9.84 1.02 3.26 - 69.2 1.04 13.52 4.52
Sesquiterpene oxygenate (SO) 2.08 0.06 8.82 6.13 6.91 4.46 1.08 - 4.21 24.03 3.18 3.95
Total Sesquiterpene 11.96 1.91 30.7 12.37 16.75 5.48 4.34 - 73.41 25.07 16.70 8.47
Others 1.62 1.94 0.94 2.34 1.25 1.97 1.25 2.96 0.11 17.29 0.57 1.02
Total 100 100 100 100 100 100 100 100 100 100 100 100

RI: calculated retention indices relative to n-alkanes (C10–C35); Compounds identified by using comparison with standards were marked with an asterisk (*).