Table 1.
Nr. Crt. | RI | Compound Name | Class | TV EO |
TV HD |
TP EO |
TP HD |
LA EO |
LA HD |
LI EO |
LI HD |
OV EO |
OV HD |
OVA EO |
OVA HD |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
1 | 930 | α-Thujene | MH | 0.89 | 0.07 | 0.04 | - | 0.53 | - | 0.26 | - | 0.07 | - | 0.75 | - |
2 | 939 | α-Pinene * | MH | 0.68 | - | 0.21 | - | - | - | 1.31 | - | 0.17 | - | 0.31 | - |
3 | 954 | Camphene | MH | 0.69 | - | 0.23 | - | 0.22 | - | 0.73 | - | - | - | 0.06 | - |
4 | 975 | Sabinene * | MH | 0.13 | - | 0.28 | - | 0.21 | - | 0.66 | - | 16.45 | 0.44 | 1.32 | 0.04 |
5 | 979 | β-Pinene * | MH | 0.31 | - | 2.19 | - | 0.69 | - | 1.48 | - | 0.65 | - | 1.31 | - |
6 | 990 | β-Myrcene * | MH | - | - | 0.07 | - | 0.24 | - | - | - | - | - | - | - |
7 | 1002 | α-Phellandrene * | MH | - | - | - | - | - | - | 0.13 | - | - | - | 0.1 | - |
8 | 1003 | 2-Carene | MH | - | - | - | - | 0.39 | - | - | - | - | - | - | - |
9 | 1011 | 3-Carene * | MH | - | - | - | - | 0.18 | - | 0.3 | - | 1.12 | - | - | - |
10 | 1012 | (+)-4-Carene | MH | 0.75 | - | - | - | - | - | 0.13 | - | 0.08 | - | 1.4 | - |
11 | 1014 | α-Terpinene | MH | - | - | 0.11 | - | - | - | - | - | - | - | 0.09 | - |
12 | 1020 | D-Limonene * | MH | 0.33 | - | 0.21 | - | - | - | 2.65 | 0.07 | - | - | - | - |
13 | 1021 | o-Cymene | MH | - | - | - | - | - | - | 0.05 | - | - | - | - | - |
14 | 1023 | m-Cymene | MH | 0.1 | - | - | - | 0.08 | - | 0.36 | - | 0.07 | - | - | - |
15 | 1024 | p-Cymene | MH | 26.4 | 2.28 | 0.07 | - | - | - | - | 0.16 | - | 1.09 | 20.81 | 2.68 |
16 | 1037 | cis-β-Ocimene * | MH | - | - | 0.16 | 0.06 | 1.21 | - | 4.92 | - | 0.6 | - | 2.71 | 0.17 |
17 | 1050 | trans-β-Ocimene * | MH | - | - | 2.14 | - | 0.13 | - | 1.58 | - | 4.96 | - | 2.57 | - |
18 | 1059 | γ-Terpinene | MH | 3.6 | 0.12 | 0.32 | - | 0.09 | 0.04 | 0.44 | - | 0.35 | - | 13.73 | 1.15 |
19 | 1088 | α- Terpinolen | MH | 0.05 | - | 0.07 | - | - | - | 0.64 | - | 0.04 | - | - | 0.07 |
20 | 1322 | Linalyl propionate | MH | - | - | - | - | 0.6 | - | - | - | - | - | - | - |
21 | Neo-allo-ocimene | MH | - | - | - | - | - | - | 0.28 | - | 0.17 | - | 0.19 | - | |
22 | ψ-Limonene | MH | 0.09 | - | - | - | - | - | 1.56 | - | - | - | - | - | |
23 | 1-Undecene, 4-methyl- | MH | - | - | - | - | - | - | - | - | - | 0.48 | - | - | |
24 | 873 | 1-Hexanol | MO | - | - | - | - | - | - | 0.3 | 0.64 | - | - | - | - |
25 | 878 | 4-Hexen-1-ol, (Z)- | MO | - | - | - | - | - | - | - | 0.08 | - | - | - | - |
26 | 963 | 3-Octanone | MO | 2.83 | - | - | - | - | - | - | - | - | 2.82 | - | - |
27 | 977 | 1-Octen-3-ol | MO | 0.87 | 1.66 | 0.3 | 0.44 | - | - | - | 0.73 | - | 13.31 | - | 1.14 |
28 | 978 | 1-Octen-3-one | MO | - | - | - | 0.36 | - | - | - | - | - | - | - | - |
29 | 980 | 3-Octanol | MO | 0.9 | 0.82 | - | 0.15 | - | - | - | - | - | 2.59 | - | - |
30 | 1010 | Acetic acid, hexyl ester | MO | - | - | - | - | - | - | 0.14 | 0.06 | - | - | - | - |
31 | 1029 | Eucalyptol | MO | - | - | 0.37 | 1.12 | 9.16 | 20.8 | 18.97 | 24.38 | 0.15 | 5.39 | - | - |
32 | 1070 | cis-Sabinene hydrate | MO | 2.3 | 0.62 | 1.58 | - | 0.45 | - | - | - | - | - | - | - |
33 | 1073 | cis-Linalool oxide | MO | - | - | - | - | - | 1.92 | - | 0.61 | - | - | - | 2.79 |
34 | 1089 | trans-Linalool oxide | MO | - | - | - | - | - | 0.98 | - | 0.45 | - | - | - | 2.18 |
35 | 1096 | Linalool | MO | - | 0.65 | 0.6 | 0.23 | 16.15 | 22.47 | 28.77 | 29.83 | 0.23 | 11.59 | 26.54 | 54.09 |
36 | 1099 | trans-Sabinene hydrate | MO | 0.44 | - | - | 1.03 | - | - | 0.37 | - | - | 0.97 | 0.11 | 1.08 |
37 | 1105 | Propanoic acid, hexyl ester | MO | - | - | - | - | - | - | 0.06 | - | - | - | - | - |
38 | 1130 | 2-Pinen-7-one | MO | - | - | - | 0.42 | - | - | - | - | - | - | - | - |
39 | 1135 | Limonene oxide | MO | - | - | - | - | 0.34 | 0.3 | - | - | - | - | - | - |
40 | 1138 | Limonene epoxide | MO | - | - | - | 0.1 | - | - | - | - | - | - | - | - |
41 | 1142 | cis verbenol | MO | - | - | 0.86 | - | - | - | - | - | - | - | - | - |
42 | 1144 | trans-Sabinol | MO | 0.03 | - | - | - | - | - | - | 0.09 | - | - | - | - |
43 | 1145 | trans-Verbenol | MO | 0.05 | - | 1.19 | - | - | - | - | - | - | - | - | - |
44 | 1146 | Camphor | MO | 0.04 | - | 0.46 | 0.38 | 4.35 | 16.94 | 4.32 | 9.21 | - | 1.02 | - | - |
45 | 1147 | Nopinone | MO | - | - | - | - | - | - | - | 0.16 | - | - | - | - |
46 | 1148 | 6-Octenal, 7-methyl-3-methylene- | MO | - | - | - | 0.54 | - | - | - | - | - | - | - | - |
47 | 1153 | Camphene hydrate | MO | - | - | - | - | - | - | - | 0.05 | - | - | - | - |
48 | 1156 | Neryl oxide | MO | - | - | - | 0.14 | - | - | - | - | - | - | - | - |
49 | 1163 | Pinocarvone | MO | - | - | - | - | - | - | - | 0.03 | - | - | - | - |
50 | 1165 | Isoneral | MO | - | - | - | 0.7 | - | - | - | - | - | - | - | - |
51 | 1168 | Lavandulol | MO | - | - | - | - | - | - | 0.65 | 0.84 | - | - | - | - |
52 | 1169 | endo-Borneol | MO | 1.85 | 2.42 | 1.58 | 0.15 | 3.25 | 6.55 | 9.3 | 13.65 | - | 1.07 | - | - |
53 | 1177 | Terpinen-4-ol | MO | 0.17 | - | 0.25 | - | 2.83 | 7.92 | 5.48 | 10.45 | 0.02 | 4.94 | 0.2 | - |
54 | 1184 | Isogeranial | MO | 0.05 | - | - | 1.33 | - | - | - | - | - | 0.25 | - | 0.13 |
55 | 1188 | α-Terpineol | MO | 0.1 | - | 0.21 | 0.1 | 0.85 | 4.36 | 0.95 | 3.17 | 0.09 | 6.16 | 0.19 | - |
56 | 1190 | Methyl salicylate | MO | - | - | - | - | - | - | - | - | - | - | 0.13 | - |
57 | 1194 | Butanoic acid, hexyl ester | MO | - | - | - | - | - | - | 0.86 | - | - | - | - | - |
58 | 1199 | Estragole | MO | - | - | - | 0.25 | - | - | - | - | - | - | - | - |
59 | 1206 | cis-Verbenone | MO | - | - | 0.16 | - | - | - | - | 0.05 | - | - | - | - |
60 | 1209 | trans-Piperitol | MO | - | - | - | - | - | - | - | 0.05 | - | - | - | - |
61 | 1227 | Citronellol | MO | - | - | - | 0.28 | - | - | - | - | - | - | - | - |
62 | 1232 | cis-Geraniol | MO | - | - | - | 2.18 | - | - | 0.07 | 0.65 | - | - | - | - |
63 | 1235 | Thymol methyl ether | MO | 10.78 | 0.56 | - | - | - | - | - | - | 0.28 | - | - | - |
64 | 1237 | Butanoic acid, 2-methyl-, hexyl ester | MO | - | - | - | - | - | - | 0.39 | - | - | - | - | - |
65 | 1239 | β-Citral | MO | - | - | 20.3 | 27.7 | - | - | - | - | - | - | - | - |
66 | 1241 | Isobornyl formate | MO | - | - | - | - | 0.07 | - | - | - | - | - | - | - |
67 | 1244 | Carvacrol methyl ether | MO | 6.26 | 1.64 | - | - | - | - | - | - | - | - | 3.04 | 0.97 |
68 | 1246 | D-Carvone | MO | - | - | - | - | - | - | - | 0.15 | - | 0.18 | - | - |
69 | 1252 | (-)-cis-Myrtanol | MO | - | - | - | 0.31 | - | - | - | - | - | - | - | - |
70 | 1254 | Geraniol | MO | - | - | - | 2.03 | - | - | - | - | - | - | - | - |
71 | 1255 | Piperitone | MO | - | - | - | 0.12 | - | - | 0.04 | 0.1 | - | - | - | - |
72 | 1258 | Linalyl acetate | MO | - | - | - | 0.28 | 36.7 | 5.69 | 3.73 | 0.19 | 0.55 | - | - | - |
73 | 1264 | (-)-trans-Myrtanol | MO | - | - | 0.17 | - | - | - | - | - | - | - | - | - |
74 | 1268 | Geranial | MO | - | - | 20.66 | 37.91 | - | - | - | - | - | - | - | - |
75 | 1287 | Bornyl acetate | MO | - | 0.36 | 0.2 | - | - | - | 0.29 | 0.07 | - | - | - | - |
76 | 1290 | Thymol | MO | 15.52 | 62.96 | 9.7 | - | - | - | - | - | 0.21 | 1.92 | 6.88 | 21.96 |
77 | 1292 | Lavandulyl acetate | MO | - | - | - | 1.99 | 3.14 | 0.81 | 0.99 | - | - | - | - | - |
78 | 1299 | Carvacrol * | MO | 1.85 | 21.48 | 0.34 | - | - | - | - | - | 0.08 | 0.43 | - | 0.45 |
79 | 1333 | Hexyl tiglate | MO | - | - | - | - | - | - | 0.15 | - | - | - | - | - |
80 | 1352 | Thymol acetate | MO | 0.05 | - | - | - | - | - | - | - | - | - | - | - |
81 | 1381 | Nerol acetate | MO | - | - | 3.33 | 3.24 | 0.14 | 0.19 | 0.11 | - | - | - | - | - |
82 | 1384 | Hexanoic acid, hexyl ester | MO | - | - | - | - | - | - | 0.19 | - | - | - | - | - |
83 | 1435 | Coumarin | MO | - | - | - | - | - | 1.54 | - | 0.13 | - | - | - | - |
84 | α-Limonene diepoxide | MO | - | - | - | - | - | 1.63 | - | - | - | - | - | - | |
85 | cis-p-Mentha-2-en-1-ol | MO | - | - | - | - | - | - | 0.07 | 0.15 | - | - | - | - | |
86 | Linalyl formate | MO | - | - | - | - | - | 0.09 | 0.09 | - | - | - | - | - | |
87 | trans-Pyranoid linalool oxide | MO | - | - | - | - | - | - | - | 0.07 | - | - | - | - | |
88 | n-Hexyl butanoate | MO | - | - | - | - | - | - | - | 0.05 | - | - | - | - | |
89 | (-)-trans-Isopiperitenol | MO | - | - | - | - | - | - | - | 0.04 | - | - | - | - | |
90 | 2-Caren-4-ol | MO | - | - | - | - | - | - | 0.05 | 0.13 | - | - | - | - | |
91 | Cumic aldehyde | MO | - | - | - | - | - | - | 0.47 | 0.25 | - | - | - | - | |
92 | p-Cymen-7-ol | MO | 0.14 | - | - | - | - | - | 0.12 | 0.23 | - | - | - | - | |
93 | Car-3-en-5-one | MO | - | - | - | 0.12 | - | 0.32 | - | 0.07 | - | - | - | - | |
94 | p-Cymen-8-ol | MO | 0.08 | - | - | - | - | - | - | - | - | - | - | 0.9 | |
95 | 8,9-Dehydrothymol methyl ether | MO | 0.17 | - | - | - | - | - | - | - | - | - | - | - | |
96 | 3-Carene-2,5-dione | MO | 7.9 | - | - | - | - | - | - | - | - | - | - | - | |
97 | 2,4-Di-tert-butylphenol | MO | - | 0.51 | - | - | - | - | - | - | - | - | - | - | |
98 | 1-Nonen-3-ol | MO | - | - | - | 0.12 | - | - | - | - | - | 0.99 | - | - | |
99 | Rosefuran | MO | - | - | - | 0.05 | - | - | - | - | - | - | 0.03 | - | |
100 | p-Menth-1-en-7-al | MO | - | - | - | 0.31 | - | - | - | - | - | - | - | - | |
101 | p-Menth-3-en-9-ol | MO | - | - | - | 0.36 | - | - | - | - | - | - | - | - | |
102 | trans-3(10)-Caren-2-ol | MO | - | - | - | 0.29 | - | - | - | - | - | - | - | - | |
103 | Hydroxy-α-terpenyl acetate | MO | - | - | - | 0.12 | - | - | - | - | - | - | - | - | |
104 | Isothymol methyl ether | MO | - | - | - | - | - | - | - | - | 0.02 | - | - | - | |
105 | Dihydroedulan | MO | - | - | - | - | - | - | - | - | 0.12 | 0.28 | 0.26 | 0.71 | |
106 | cis-p-2-Menthen-1-ol | MO | - | - | - | - | - | - | - | - | - | 0.45 | - | - | |
107 | 3-p-Menthen-7-al | MO | - | - | - | - | - | - | - | - | - | 0.17 | - | - | |
108 | 2,4-Di-tert-butylphenol | MO | - | - | - | - | - | - | - | - | - | 1.1 | - | - | |
109 | Limonene diepoxide | MO | 0.02 | - | - | 0.3 | - | - | - | - | - | - | - | - | |
110 | p-Cymen-8-ol | MO | - | - | - | - | - | - | - | - | - | - | - | - | |
111 | 1376 | α-Copaene | SH | 0.05 | 0.07 | - | - | - | - | - | - | 0.15 | - | 0.26 | - |
112 | 1378 | isoledene | SH | 0.14 | - | - | - | 0.25 | - | 0.03 | - | - | - | 0.43 | - |
113 | 1389 | (-)-β-Bourbonene | SH | 0.29 | - | 1.22 | 0.3 | - | - | - | - | 1.65 | 0.47 | 0.52 | - |
114 | 1391 | β-Elemen | SH | - | - | 0.57 | 0.16 | - | - | - | - | 0.51 | - | 0.21 | - |
115 | 1402 | Sesquithujene | SH | - | - | - | - | - | - | 0.07 | - | - | - | - | - |
116 | 1405 | β-Longipinene | SH | 0.03 | - | - | - | - | - | - | - | - | - | - | - |
117 | 1408 | Isocaryophyllene | SH | - | - | 0.24 | 1.49 | 2.16 | - | 2.26 | - | 13.41 | - | 3.04 | - |
118 | 1414 | cis-α-Bergamotene | SH | 0.03 | - | 0.03 | - | 0.29 | - | 0.08 | - | 1 | - | 0.11 | - |
119 | 1419 | β-Caryophyllene * | SH | 3.14 | 0.64 | 0.96 | - | 2.69 | 0.22 | 0.46 | - | - | 0.32 | 0.98 | 0.23 |
120 | 1422 | β-Cedrene | SH | 0.1 | - | - | - | 0.55 | 0.08 | 0.04 | - | - | - | - | - |
121 | 1432 | β-Copaene | SH | 0.15 | - | 0.12 | 0.08 | - | - | - | - | 0.72 | - | 0.19 | - |
122 | 1440 | α-Guaiene | SH | 0.04 | - | - | - | - | - | - | - | - | - | 0.46 | - |
123 | 1441 | Aromandendrene | SH | 4.4 | 0.86 | 1.97 | 0.06 | - | - | - | - | - | - | - | 1.12 |
124 | 1444 | β-Farnesene | SH | - | - | 0.32 | - | - | - | - | - | - | - | - | - |
125 | 1447 | Isogermacrene D | SH | - | - | 0.42 | - | - | - | - | - | - | - | - | - |
126 | 1454 | Humulene | SH | 0.13 | - | - | - | - | - | - | - | 3.08 | - | 0.22 | - |
127 | 1456 | trans-α-Bergamotene | SH | - | - | - | - | - | - | - | - | 0.19 | - | - | - |
128 | 1459 | γ-Elemene | SH | - | - | - | - | - | - | - | - | 0.37 | - | - | - |
129 | 1468 | cis-Muurola-4(15),5-diene | SH | - | - | - | - | - | - | - | - | 1.16 | - | - | - |
130 | 1479 | γ-Muurolene | SH | 0.16 | - | 0.31 | - | - | - | 0.07 | - | 0.19 | - | 0.11 | - |
131 | 1481 | Germacrene D | SH | 1.03 | 0.28 | 15.34 | 3.67 | 2.49 | 0.23 | 0.13 | - | 22.63 | - | 5.98 | 2.59 |
132 | 1498 | Valencene | SH | 0.05 | - | - | - | - | - | - | - | - | - | 0.16 | - |
133 | 1502 | Bicyclogermacrene | SH | - | - | - | 0.21 | - | - | - | - | 5.18 | - | 0.56 | - |
134 | 1507 | α-Farnesene | SH | - | - | 0.34 | - | 0.14 | - | 0.1 | - | 15.64 | - | - | - |
135 | 1509 | α-Bisabolene | SH | - | - | 0.04 | 0.12 | 0.35 | 0.07 | - | - | 2.22 | - | 0.13 | - |
136 | 1512 | γ-Cadinene | SH | 0.14 | - | - | - | 0.92 | 0.19 | 0.02 | - | 0.58 | - | 0.16 | 0.58 |
137 | 1523 | β-Sesquiphellandrene | SH | - | - | - | 0.15 | - | - | - | - | - | - | - | - |
138 | 1544 | Nerolidol | SH | - | - | - | - | - | 0.23 | - | - | - | 0.25 | - | - |
139 | Cadina-3,5-diene | SH | - | - | - | - | - | - | - | - | 0.52 | - | - | - | |
140 | 1513 | (R)-lavandulyl (R)-2-methylbutanoate | SO | - | - | - | - | - | - | 0.33 | - | - | - | - | - |
141 | 1561 | Nerolidol | SO | - | - | - | 1.04 | - | - | - | - | - | - | - | - |
142 | 1562 | Elemol | SO | - | - | 0.6 | 4.32 | - | - | - | - | - | - | - | - |
143 | 1580 | Germacren D-4-ol | SO | - | - | 0.19 | - | - | - | - | - | 2.97 | - | - | - |
144 | 1582 | (-)-Spathulenol | SO | 0.29 | - | - | 0.1 | - | - | - | - | - | 5.64 | 0.73 | 1.55 |
145 | 1583 | Caryophyllene oxide | SO | 1.4 | 0.06 | - | - | 0.4 | 0.25 | 0.1 | - | - | 12.44 | 0.67 | 0.73 |
146 | 1615 | Humulene oxide | SO | 0.03 | - | - | - | - | - | - | - | - | - | 0.27 | - |
147 | 1631 | γ-Eudesmol | SO | - | - | - | 0.19 | - | - | - | - | - | - | - | - |
148 | 1632 | Epicubenol | SO | - | - | - | - | 0.12 | 0.11 | - | - | 0.23 | 0.68 | - | - |
149 | 1640 | τ-Cadinol | SO | - | - | - | - | 2.45 | 1.84 | - | - | 0.47 | 2.86 | 0.26 | 0.39 |
150 | 1641 | Alloaromadendrene oxide-(1) | SO | - | - | - | - | - | - | - | - | - | 0.4 | 0.1 | - |
151 | 1642 | τ-Muurolol | SO | 0.06 | - | - | - | - | - | - | - | 0.21 | - | 0.16 | 0.37 |
152 | 1644 | Aromadendrene oxide-(2) | SO | 0.06 | - | - | - | - | - | - | - | - | 0.4 | - | - |
153 | 1648 | α-Muurolol | SO | - | - | - | - | - | - | - | - | - | 1.19 | - | - |
154 | 1654 | α-Eudesmol | SO | - | - | - | 0.4 | - | - | - | - | - | - | - | - |
155 | 1682 | Nerolidyl acetate | SO | - | - | 8.03 | - | - | - | - | - | - | - | - | - |
156 | 1687 | α-Bisabolol | SO | - | - | - | - | 3.48 | 2.26 | 0.65 | - | 0.33 | - | - | - |
157 | 1692 | Shyobunol | SO | - | - | - | - | 0.46 | - | - | - | - | - | 0.99 | 0.91 |
158 | 1696 | Farnesol | SO | - | - | - | 0.08 | - | - | - | - | - | - | - | - |
159 | 1762 | cis-Lanceol | SO | 0.17 | - | - | - | - | - | - | - | - | - | - | - |
160 | 1765 | 15-Hydroxy-α-muurolene | SO | 0.07 | - | - | - | - | - | - | - | - | - | - | - |
161 | Aromadendrane-4,10-diol | SO | - | - | - | - | - | - | - | - | - | 0.42 | - | - | |
Total unidentified (%) | 1.57 | 1.94 | 0.87 | 2.34 | 1.25 | 1.97 | 1.25 | 2.96 | 0.07 | 17.29 | 0.57 | 1.02 | |||
Total identified (%) | 98.43 | 98.06 | 99.13 | 99.68 | 98.75 | 98.03 | 98.75 | 97.09 | 99.93 | 83.21 | 99.49 | 98.98 | |||
Total of Major Compounds (%) | |||||||||||||||
Monoterpene hydrocarbonates (MH) | 34.02 | 2.47 | 6.1 | 0.06 | 4.57 | 0.04 | 17.48 | 0.23 | 24.73 | 2.01 | 45.35 | 4.11 | |||
Monoterpenes oxygenate (MO) | 52.4 | 93.68 | 62.26 | 85.15 | 77.43 | 92.51 | 76.93 | 96.81 | 1.75 | 55.63 | 37.38 | 86.4 | |||
Total Monoterpene | 86.42 | 96.15 | 68.36 | 85.21 | 82 | 92.55 | 94.41 | 97.03 | 26.48 | 57.64 | 82.73 | 90.51 | |||
Sesquiterpene hydrocarbonates (SH) | 9.88 | 1.85 | 21.88 | 6.24 | 9.84 | 1.02 | 3.26 | - | 69.2 | 1.04 | 13.52 | 4.52 | |||
Sesquiterpene oxygenate (SO) | 2.08 | 0.06 | 8.82 | 6.13 | 6.91 | 4.46 | 1.08 | - | 4.21 | 24.03 | 3.18 | 3.95 | |||
Total Sesquiterpene | 11.96 | 1.91 | 30.7 | 12.37 | 16.75 | 5.48 | 4.34 | - | 73.41 | 25.07 | 16.70 | 8.47 | |||
Others | 1.62 | 1.94 | 0.94 | 2.34 | 1.25 | 1.97 | 1.25 | 2.96 | 0.11 | 17.29 | 0.57 | 1.02 | |||
Total | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 | 100 |
RI: calculated retention indices relative to n-alkanes (C10–C35); Compounds identified by using comparison with standards were marked with an asterisk (*).