Table 3.

Analytical methods used in glyphosate detection and quantification.

Matrix	Extraction Method	Analytical Method	LOD (μg/kg)	LOQ (μg/kg)	References
Honey Fish Beef	Sonication with a mixture of acidified water at 1% and methanol (7:3)	IC-HRMS	nd	43 51 65	[6]
Honey	SPE followed by derivatization	HPLC-MS/MS	nd	1	[19]
Honey	Centrifugation with methanol	UHPLC-MS/MS	nd	50	[79]
Yam	Centrifugation followed by derivatization	HPLC-MS/MS	40	120	[13]
Yam Grape Chickpea	SPE	FI-MS/MS	nd	500 500 2000	[80]
Fruits and Vegetables	Centrifugation with a mixture of water and methanol (1:1)	IC-MS/MS	25	nd	[81]
Fruits juice Vegetables Fruit puree	Centrifugation with acidified methanol	UHPLC-MS/MS	nd	3	[82]
Grape	SPE	HPLC-MS/MS	60	190	[83]
Fruits and Vegetables	SPE	HPLC-MS/MS	1.2	5	[84]
Guava	SPE	CE-ECL	10	nd	[85]
Wheat	SPE followed by derivatization	FASI-MEKC	30	100	[86]
Rice Corn	Centrifugation with a mixture of water and acidified methanol at 1% (1:1)	HPLC-MS/MS	2 4	10	[87]
Cereals	Ultrasonication with water	HPLC-MS/MS	20	nd	[88]
Soy Corn	SPE	HPLC-MS/MS	140 150	420 450	[89]
Oil	Centrifugation with acidified water at 1%	HPLC-MS/MS	3.3	10	[43]
Beer	SPE	HPLC-MS/MS	0.2	0.5	[90]
Several aliments Several beverages	SPE	HPLC-MS/MS	0.3 0.2	1 0.5	[47]
Several aliments	SPE followed by derivatization	HPLC-MS/MS	1.7	5	[91]

CE-ECL—Capillary Electrophoresis with Electrochemiluminescence. FASI-MEKC—Field-Amplified Sample Injection and Sweeping Micellar Electrokinetic Chromatography. FI-MS/MS—Flow Injection with tandem Mass Spectrometry. HPLC-MS/MS—High Performance Liquid Chromatography-tandem Spectrometry Mass. IC-HRMS—Ion Chromatography with tandem High Resolution Mass Spectrometry. IC-MS/MS—Ion Chromatography with tandem Mass Spectrometry. nd—Not defined. SPE—Solid Phase Extraction. UHPLC-MS/MS—Ultra High Performance Liquid Chromatography with tandem Mass Spectrometry.