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(A) Previous methodologies for the α-functionalization of saturated azacycles. (B) Our recent methodology for the α-functionalization of saturated azacycles. (C) Investigations of the selectivity of the Norrish–Yang cyclization (NYC) and palladium-mediated cleavage/cross-coupling of a cyclopropane-fused piperidine. (D) Mechanistic proposal for the C–C cleavage cross-coupling reaction.
