| Crystal data |
| Chemical formula |
[TbCu5(C2H4N2O2)5(SO4)(H2O)6.5]2(SO4)·6H2O |
|
M
r
|
2464.44 |
| Crystal system, space group |
Triclinic, P\overline{1} |
| Temperature (K) |
150 |
|
a, b, c (Å) |
9.6370 (4), 11.5888 (5), 16.2367 (6) |
| α, β, γ (°) |
99.6716 (13), 91.3031 (12), 105.3123 (12) |
|
V (Å3) |
1719.80 (12) |
|
Z
|
1 |
| Radiation type |
Cu Kα |
| μ (mm−1) |
15.11 |
| Crystal size (mm) |
0.20 × 0.20 × 0.08 |
| |
| Data collection |
| Diffractometer |
Bruker AXS D8 Quest CMOS diffractometer with PhotonII charge-integrating pixel array detector (CPAD) |
| Absorption correction |
Multi-scan (SADABS; Krause et al., 2015 ▸
|
|
T
min, T
max
|
0.454, 0.754 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
16278, 7029, 6786 |
|
R
int
|
0.050 |
| (sin θ/λ)max (Å−1) |
0.639 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.041, 0.118, 1.10 |
| No. of reflections |
7029 |
| No. of parameters |
562 |
| No. of restraints |
22 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
1.59, −1.34 |
