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(1) Routes to SIAs: (a) oxidative imidation, (b) oxidative chlorination, (c) deoxychlorination, (d) Grignard addition and chlorination, (e) sulfur–fluorine exchange via sulfinimidoyl fluoride; (2) routes to SOIs: (f) imidation, (g) oxidation, (h) desymmetrization of SOIs, and (i) S-alkylation; and (3) this work: SIAs and SOIs via photogenerated nitrenes.
