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. 2021 Nov 20;86(23):17249–17256. doi: 10.1021/acs.joc.1c02320

Table 1. Screening of Reaction Conditions for Racemization of 1a1113.

graphic file with name jo1c02320_0012.jpg

entry catalyst wavelength (nm) t1/2 (s) k2 (M–1 s–1)
1   425    
2 A 525–530    
3 B 365    
4 C 380    
5 D 450–455    
6 E 425 106 6.57 × 101
7 F 380 71 9.82 × 101
8 G 365 30 2.28 × 102
9 H 365 5 1.36 × 103
10 H 425 2 3.19 × 103